(R)-(−)-Quinuclidin-3-ol

The structure of the title compound [alternatively called (R)-(−)-1-aza­bicyclo­[2.2.2]octan-3-ol], C(7)H(13)NO, at 100 K has hexa­gonal (P6(1)) symmetry. The structure shows a twist along the C—N pseudo-threefold axis. In the crystal, mol­ecules are linked via O—H⋯N hydrogen bonds, forming infinite...

Descripción completa

Detalles Bibliográficos
Autores principales: Rousselin, Yoann, Clavel, Alexandre, Bonnaventure, Isabelle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884330/
https://www.ncbi.nlm.nih.gov/pubmed/24454106
http://dx.doi.org/10.1107/S1600536813026998
_version_ 1782298565765234688
author Rousselin, Yoann
Clavel, Alexandre
Bonnaventure, Isabelle
author_facet Rousselin, Yoann
Clavel, Alexandre
Bonnaventure, Isabelle
author_sort Rousselin, Yoann
collection PubMed
description The structure of the title compound [alternatively called (R)-(−)-1-aza­bicyclo­[2.2.2]octan-3-ol], C(7)H(13)NO, at 100 K has hexa­gonal (P6(1)) symmetry. The structure shows a twist along the C—N pseudo-threefold axis. In the crystal, mol­ecules are linked via O—H⋯N hydrogen bonds, forming infinite chains along the c-axis direction. The crystal studied was twinned by merohedry (twin law: 010, 100, 00-1; population: 0.925:0.075)
format Online
Article
Text
id pubmed-3884330
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38843302014-01-17 (R)-(−)-Quinuclidin-3-ol Rousselin, Yoann Clavel, Alexandre Bonnaventure, Isabelle Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title compound [alternatively called (R)-(−)-1-aza­bicyclo­[2.2.2]octan-3-ol], C(7)H(13)NO, at 100 K has hexa­gonal (P6(1)) symmetry. The structure shows a twist along the C—N pseudo-threefold axis. In the crystal, mol­ecules are linked via O—H⋯N hydrogen bonds, forming infinite chains along the c-axis direction. The crystal studied was twinned by merohedry (twin law: 010, 100, 00-1; population: 0.925:0.075) International Union of Crystallography 2013-10-19 /pmc/articles/PMC3884330/ /pubmed/24454106 http://dx.doi.org/10.1107/S1600536813026998 Text en © Rousselin et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rousselin, Yoann
Clavel, Alexandre
Bonnaventure, Isabelle
(R)-(−)-Quinuclidin-3-ol
title (R)-(−)-Quinuclidin-3-ol
title_full (R)-(−)-Quinuclidin-3-ol
title_fullStr (R)-(−)-Quinuclidin-3-ol
title_full_unstemmed (R)-(−)-Quinuclidin-3-ol
title_short (R)-(−)-Quinuclidin-3-ol
title_sort (r)-(−)-quinuclidin-3-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884330/
https://www.ncbi.nlm.nih.gov/pubmed/24454106
http://dx.doi.org/10.1107/S1600536813026998
work_keys_str_mv AT rousselinyoann rquinuclidin3ol
AT clavelalexandre rquinuclidin3ol
AT bonnaventureisabelle rquinuclidin3ol

Ejemplares similares