2,4,6-Tri­nitro­phenyl furan-2-carboxyl­ate

In the title carboxyl­ate derivative, C(11)H(5)N(3)O(9), the picryl ring forms an angle of 75.79 (7)° with the ester fragment, indicating a near perpendicular disposition. The nitro substituents are variously oriented with respect to the picryl ring [dihedral angles = 3.22 (10), 16.03 (12) and 36.63...

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Autores principales: Moreno-Fuquen, Rodolfo, Mosquera, Fabricio, Kennedy, Alan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884337/
https://www.ncbi.nlm.nih.gov/pubmed/24454113
http://dx.doi.org/10.1107/S1600536813028274
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author Moreno-Fuquen, Rodolfo
Mosquera, Fabricio
Kennedy, Alan R.
author_facet Moreno-Fuquen, Rodolfo
Mosquera, Fabricio
Kennedy, Alan R.
author_sort Moreno-Fuquen, Rodolfo
collection PubMed
description In the title carboxyl­ate derivative, C(11)H(5)N(3)O(9), the picryl ring forms an angle of 75.79 (7)° with the ester fragment, indicating a near perpendicular disposition. The nitro substituents are variously oriented with respect to the picryl ring [dihedral angles = 3.22 (10), 16.03 (12) and 36.63 (10)°]. In the crystal, mol­ecules form helical chains sustained by C—H⋯O inter­actions along [010]. The furanyl residue is disordered, having two coplanar slightly displaced orientations [major component = 0.730 (9)].
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spelling pubmed-38843372014-01-17 2,4,6-Tri­nitro­phenyl furan-2-carboxyl­ate Moreno-Fuquen, Rodolfo Mosquera, Fabricio Kennedy, Alan R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title carboxyl­ate derivative, C(11)H(5)N(3)O(9), the picryl ring forms an angle of 75.79 (7)° with the ester fragment, indicating a near perpendicular disposition. The nitro substituents are variously oriented with respect to the picryl ring [dihedral angles = 3.22 (10), 16.03 (12) and 36.63 (10)°]. In the crystal, mol­ecules form helical chains sustained by C—H⋯O inter­actions along [010]. The furanyl residue is disordered, having two coplanar slightly displaced orientations [major component = 0.730 (9)]. International Union of Crystallography 2013-10-23 /pmc/articles/PMC3884337/ /pubmed/24454113 http://dx.doi.org/10.1107/S1600536813028274 Text en © Moreno-Fuquen et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moreno-Fuquen, Rodolfo
Mosquera, Fabricio
Kennedy, Alan R.
2,4,6-Tri­nitro­phenyl furan-2-carboxyl­ate
title 2,4,6-Tri­nitro­phenyl furan-2-carboxyl­ate
title_full 2,4,6-Tri­nitro­phenyl furan-2-carboxyl­ate
title_fullStr 2,4,6-Tri­nitro­phenyl furan-2-carboxyl­ate
title_full_unstemmed 2,4,6-Tri­nitro­phenyl furan-2-carboxyl­ate
title_short 2,4,6-Tri­nitro­phenyl furan-2-carboxyl­ate
title_sort 2,4,6-tri­nitro­phenyl furan-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884337/
https://www.ncbi.nlm.nih.gov/pubmed/24454113
http://dx.doi.org/10.1107/S1600536813028274
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AT mosquerafabricio 246trinitrophenylfuran2carboxylate
AT kennedyalanr 246trinitrophenylfuran2carboxylate

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