4-Methyl-N-(4-nitro­benzyl­idene)piperazin-1-amine

In the title compound, C(12)H(16)N(4)O(2), the piperazine ring is in a slightly distorted chair conformation. In the mol­ecule, the mean plane of the nitro group is twisted by 8.0 (3)° from that of the benzene ring. Also, the mean plane of the 2-nitro­benzyl ring is twisted slightly from that of the...

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Autores principales: Kavitha, Channappa N., Jasinski, Jerry P., Anderson, Brian J., Yathirajan, H.S., Kaur, Manpreet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884341/
https://www.ncbi.nlm.nih.gov/pubmed/24454117
http://dx.doi.org/10.1107/S1600536813028493
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author Kavitha, Channappa N.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H.S.
Kaur, Manpreet
author_facet Kavitha, Channappa N.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H.S.
Kaur, Manpreet
author_sort Kavitha, Channappa N.
collection PubMed
description In the title compound, C(12)H(16)N(4)O(2), the piperazine ring is in a slightly distorted chair conformation. In the mol­ecule, the mean plane of the nitro group is twisted by 8.0 (3)° from that of the benzene ring. Also, the mean plane of the 2-nitro­benzyl ring is twisted slightly from that of the piperazine ring, with an N—N=C—C torsion angle of −176.24 (11)°. In the crystal, pairs of weak C—H⋯O inter­actions link the mol­ecules into dimers approximately along [010].
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spelling pubmed-38843412014-01-17 4-Methyl-N-(4-nitro­benzyl­idene)piperazin-1-amine Kavitha, Channappa N. Jasinski, Jerry P. Anderson, Brian J. Yathirajan, H.S. Kaur, Manpreet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(16)N(4)O(2), the piperazine ring is in a slightly distorted chair conformation. In the mol­ecule, the mean plane of the nitro group is twisted by 8.0 (3)° from that of the benzene ring. Also, the mean plane of the 2-nitro­benzyl ring is twisted slightly from that of the piperazine ring, with an N—N=C—C torsion angle of −176.24 (11)°. In the crystal, pairs of weak C—H⋯O inter­actions link the mol­ecules into dimers approximately along [010]. International Union of Crystallography 2013-10-23 /pmc/articles/PMC3884341/ /pubmed/24454117 http://dx.doi.org/10.1107/S1600536813028493 Text en © Kavitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kavitha, Channappa N.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H.S.
Kaur, Manpreet
4-Methyl-N-(4-nitro­benzyl­idene)piperazin-1-amine
title 4-Methyl-N-(4-nitro­benzyl­idene)piperazin-1-amine
title_full 4-Methyl-N-(4-nitro­benzyl­idene)piperazin-1-amine
title_fullStr 4-Methyl-N-(4-nitro­benzyl­idene)piperazin-1-amine
title_full_unstemmed 4-Methyl-N-(4-nitro­benzyl­idene)piperazin-1-amine
title_short 4-Methyl-N-(4-nitro­benzyl­idene)piperazin-1-amine
title_sort 4-methyl-n-(4-nitro­benzyl­idene)piperazin-1-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884341/
https://www.ncbi.nlm.nih.gov/pubmed/24454117
http://dx.doi.org/10.1107/S1600536813028493
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