2-(3,4-Di­fluoro­phen­yl)-1H-benzimidazole

In the title mol­ecule, C(13)H(8)F(2)N(2), the dihedral angle between the benzimidazole ring system and the di­fluoro-substituted benzene ring is 30.0 (1)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, forming chains along [010]. In addition, weak C—H⋯F hydrogen bonds connect chain...

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Autores principales: Krishnamurthy, M. S., Fathima, Nikhath, Nagarajaiah, H., Begum, Noor Shahina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884342/
https://www.ncbi.nlm.nih.gov/pubmed/24454118
http://dx.doi.org/10.1107/S1600536813028559
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author Krishnamurthy, M. S.
Fathima, Nikhath
Nagarajaiah, H.
Begum, Noor Shahina
author_facet Krishnamurthy, M. S.
Fathima, Nikhath
Nagarajaiah, H.
Begum, Noor Shahina
author_sort Krishnamurthy, M. S.
collection PubMed
description In the title mol­ecule, C(13)H(8)F(2)N(2), the dihedral angle between the benzimidazole ring system and the di­fluoro-substituted benzene ring is 30.0 (1)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, forming chains along [010]. In addition, weak C—H⋯F hydrogen bonds connect chains into a two-dimensional network parallel to (001). A weak C—H⋯π inter­action is observed between an H atom of the benzimidazole ring sytem and the π system of the di­fluoro-substituted benzene ring.
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spelling pubmed-38843422014-01-17 2-(3,4-Di­fluoro­phen­yl)-1H-benzimidazole Krishnamurthy, M. S. Fathima, Nikhath Nagarajaiah, H. Begum, Noor Shahina Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(13)H(8)F(2)N(2), the dihedral angle between the benzimidazole ring system and the di­fluoro-substituted benzene ring is 30.0 (1)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, forming chains along [010]. In addition, weak C—H⋯F hydrogen bonds connect chains into a two-dimensional network parallel to (001). A weak C—H⋯π inter­action is observed between an H atom of the benzimidazole ring sytem and the π system of the di­fluoro-substituted benzene ring. International Union of Crystallography 2013-10-23 /pmc/articles/PMC3884342/ /pubmed/24454118 http://dx.doi.org/10.1107/S1600536813028559 Text en © Krishnamurthy et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Krishnamurthy, M. S.
Fathima, Nikhath
Nagarajaiah, H.
Begum, Noor Shahina
2-(3,4-Di­fluoro­phen­yl)-1H-benzimidazole
title 2-(3,4-Di­fluoro­phen­yl)-1H-benzimidazole
title_full 2-(3,4-Di­fluoro­phen­yl)-1H-benzimidazole
title_fullStr 2-(3,4-Di­fluoro­phen­yl)-1H-benzimidazole
title_full_unstemmed 2-(3,4-Di­fluoro­phen­yl)-1H-benzimidazole
title_short 2-(3,4-Di­fluoro­phen­yl)-1H-benzimidazole
title_sort 2-(3,4-di­fluoro­phen­yl)-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884342/
https://www.ncbi.nlm.nih.gov/pubmed/24454118
http://dx.doi.org/10.1107/S1600536813028559
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