1-Acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one

In the title compound, C(11)H(9)FN(2)O(2)S, the 2-sulfanylideneimidazolidin-4-one moiety is essentially planar, with a maximum deviation of 0.0183 (14) Å. The mean plane of this moiety is approximately coplanar with the attached acetyl group and perpendicular to the benzene ring, making dihedral ang...

Descripción completa

Detalles Bibliográficos
Autores principales: Kitoh, Soh-ichi, Feng, Yijing, Fujinami, Shuhei, Ichitani, Masaki, Honda, Mitsunori, Kunimoto, Ko-Ki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884349/
https://www.ncbi.nlm.nih.gov/pubmed/24454125
http://dx.doi.org/10.1107/S1600536813028560
_version_ 1782298570187079680
author Kitoh, Soh-ichi
Feng, Yijing
Fujinami, Shuhei
Ichitani, Masaki
Honda, Mitsunori
Kunimoto, Ko-Ki
author_facet Kitoh, Soh-ichi
Feng, Yijing
Fujinami, Shuhei
Ichitani, Masaki
Honda, Mitsunori
Kunimoto, Ko-Ki
author_sort Kitoh, Soh-ichi
collection PubMed
description In the title compound, C(11)H(9)FN(2)O(2)S, the 2-sulfanylideneimidazolidin-4-one moiety is essentially planar, with a maximum deviation of 0.0183 (14) Å. The mean plane of this moiety is approximately coplanar with the attached acetyl group and perpendicular to the benzene ring, making dihedral angles of 9.70 (14) and 86.70 (6)°, respectively. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds between the amide NH and acetyl C=O groups, forming a C(6) chain along the a-axis direction.
format Online
Article
Text
id pubmed-3884349
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38843492014-01-17 1-Acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one Kitoh, Soh-ichi Feng, Yijing Fujinami, Shuhei Ichitani, Masaki Honda, Mitsunori Kunimoto, Ko-Ki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(9)FN(2)O(2)S, the 2-sulfanylideneimidazolidin-4-one moiety is essentially planar, with a maximum deviation of 0.0183 (14) Å. The mean plane of this moiety is approximately coplanar with the attached acetyl group and perpendicular to the benzene ring, making dihedral angles of 9.70 (14) and 86.70 (6)°, respectively. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds between the amide NH and acetyl C=O groups, forming a C(6) chain along the a-axis direction. International Union of Crystallography 2013-10-23 /pmc/articles/PMC3884349/ /pubmed/24454125 http://dx.doi.org/10.1107/S1600536813028560 Text en © Kitoh et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kitoh, Soh-ichi
Feng, Yijing
Fujinami, Shuhei
Ichitani, Masaki
Honda, Mitsunori
Kunimoto, Ko-Ki
1-Acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one
title 1-Acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one
title_full 1-Acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one
title_fullStr 1-Acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one
title_full_unstemmed 1-Acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one
title_short 1-Acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one
title_sort 1-acetyl-5-(4-fluoro­phen­yl)-2-sulfanyl­ideneimidazolidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884349/
https://www.ncbi.nlm.nih.gov/pubmed/24454125
http://dx.doi.org/10.1107/S1600536813028560
work_keys_str_mv AT kitohsohichi 1acetyl54fluorophenyl2sulfanylideneimidazolidin4one
AT fengyijing 1acetyl54fluorophenyl2sulfanylideneimidazolidin4one
AT fujinamishuhei 1acetyl54fluorophenyl2sulfanylideneimidazolidin4one
AT ichitanimasaki 1acetyl54fluorophenyl2sulfanylideneimidazolidin4one
AT hondamitsunori 1acetyl54fluorophenyl2sulfanylideneimidazolidin4one
AT kunimotokoki 1acetyl54fluorophenyl2sulfanylideneimidazolidin4one

Ejemplares similares