Cargando…

6-(4-Chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole

In the title compound, C(12)H(9)ClN(2)S, the imidazo[2,1-b]thia­zole fragment is planar (r.m.s. deviation = 0.003 Å), and the benzene ring is twisted slightly [by 5.65 (6)°] relative to this moiety. In the crystal, mol­ecules are linked by π–π stacking inter­actions into columns along [010]. The mol...

Descripción completa

Detalles Bibliográficos
Autores principales: Bunev, Alexander S., Sukhonosova, Elena V., Statsyuk, Vladimir E., Ostapenko, Gennady I., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884351/
https://www.ncbi.nlm.nih.gov/pubmed/24454127
http://dx.doi.org/10.1107/S1600536813028833
_version_ 1782298570644258816
author Bunev, Alexander S.
Sukhonosova, Elena V.
Statsyuk, Vladimir E.
Ostapenko, Gennady I.
Khrustalev, Victor N.
author_facet Bunev, Alexander S.
Sukhonosova, Elena V.
Statsyuk, Vladimir E.
Ostapenko, Gennady I.
Khrustalev, Victor N.
author_sort Bunev, Alexander S.
collection PubMed
description In the title compound, C(12)H(9)ClN(2)S, the imidazo[2,1-b]thia­zole fragment is planar (r.m.s. deviation = 0.003 Å), and the benzene ring is twisted slightly [by 5.65 (6)°] relative to this moiety. In the crystal, mol­ecules are linked by π–π stacking inter­actions into columns along [010]. The mol­ecules within the columns are arranged alternatively by their planar rotation of 180°. Thus, in the columns, there are the two types of π–π stacking inter­actions, namely, (i) between two imidazo[2,1-b]thia­zole fragments [inter­planar distance = 3.351 (2) Å] and (ii) between an imidazo[2,1-b]thia­zole fragment and the phenyl ring [inter­planar distance = 3.410 (5) Å]. There are no short contacts between the columns.
format Online
Article
Text
id pubmed-3884351
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38843512014-01-17 6-(4-Chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole Bunev, Alexander S. Sukhonosova, Elena V. Statsyuk, Vladimir E. Ostapenko, Gennady I. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(9)ClN(2)S, the imidazo[2,1-b]thia­zole fragment is planar (r.m.s. deviation = 0.003 Å), and the benzene ring is twisted slightly [by 5.65 (6)°] relative to this moiety. In the crystal, mol­ecules are linked by π–π stacking inter­actions into columns along [010]. The mol­ecules within the columns are arranged alternatively by their planar rotation of 180°. Thus, in the columns, there are the two types of π–π stacking inter­actions, namely, (i) between two imidazo[2,1-b]thia­zole fragments [inter­planar distance = 3.351 (2) Å] and (ii) between an imidazo[2,1-b]thia­zole fragment and the phenyl ring [inter­planar distance = 3.410 (5) Å]. There are no short contacts between the columns. International Union of Crystallography 2013-10-26 /pmc/articles/PMC3884351/ /pubmed/24454127 http://dx.doi.org/10.1107/S1600536813028833 Text en © Bunev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bunev, Alexander S.
Sukhonosova, Elena V.
Statsyuk, Vladimir E.
Ostapenko, Gennady I.
Khrustalev, Victor N.
6-(4-Chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole
title 6-(4-Chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole
title_full 6-(4-Chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole
title_fullStr 6-(4-Chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole
title_full_unstemmed 6-(4-Chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole
title_short 6-(4-Chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole
title_sort 6-(4-chloro­phen­yl)-3-methyl­imidazo[2,1-b]thia­zole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884351/
https://www.ncbi.nlm.nih.gov/pubmed/24454127
http://dx.doi.org/10.1107/S1600536813028833
work_keys_str_mv AT bunevalexanders 64chlorophenyl3methylimidazo21bthiazole
AT sukhonosovaelenav 64chlorophenyl3methylimidazo21bthiazole
AT statsyukvladimire 64chlorophenyl3methylimidazo21bthiazole
AT ostapenkogennadyi 64chlorophenyl3methylimidazo21bthiazole
AT khrustalevvictorn 64chlorophenyl3methylimidazo21bthiazole