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6-(4-Chlorophenyl)-3-methylimidazo[2,1-b]thiazole
In the title compound, C(12)H(9)ClN(2)S, the imidazo[2,1-b]thiazole fragment is planar (r.m.s. deviation = 0.003 Å), and the benzene ring is twisted slightly [by 5.65 (6)°] relative to this moiety. In the crystal, molecules are linked by π–π stacking interactions into columns along [010]. The mol...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884351/ https://www.ncbi.nlm.nih.gov/pubmed/24454127 http://dx.doi.org/10.1107/S1600536813028833 |
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author | Bunev, Alexander S. Sukhonosova, Elena V. Statsyuk, Vladimir E. Ostapenko, Gennady I. Khrustalev, Victor N. |
author_facet | Bunev, Alexander S. Sukhonosova, Elena V. Statsyuk, Vladimir E. Ostapenko, Gennady I. Khrustalev, Victor N. |
author_sort | Bunev, Alexander S. |
collection | PubMed |
description | In the title compound, C(12)H(9)ClN(2)S, the imidazo[2,1-b]thiazole fragment is planar (r.m.s. deviation = 0.003 Å), and the benzene ring is twisted slightly [by 5.65 (6)°] relative to this moiety. In the crystal, molecules are linked by π–π stacking interactions into columns along [010]. The molecules within the columns are arranged alternatively by their planar rotation of 180°. Thus, in the columns, there are the two types of π–π stacking interactions, namely, (i) between two imidazo[2,1-b]thiazole fragments [interplanar distance = 3.351 (2) Å] and (ii) between an imidazo[2,1-b]thiazole fragment and the phenyl ring [interplanar distance = 3.410 (5) Å]. There are no short contacts between the columns. |
format | Online Article Text |
id | pubmed-3884351 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38843512014-01-17 6-(4-Chlorophenyl)-3-methylimidazo[2,1-b]thiazole Bunev, Alexander S. Sukhonosova, Elena V. Statsyuk, Vladimir E. Ostapenko, Gennady I. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(9)ClN(2)S, the imidazo[2,1-b]thiazole fragment is planar (r.m.s. deviation = 0.003 Å), and the benzene ring is twisted slightly [by 5.65 (6)°] relative to this moiety. In the crystal, molecules are linked by π–π stacking interactions into columns along [010]. The molecules within the columns are arranged alternatively by their planar rotation of 180°. Thus, in the columns, there are the two types of π–π stacking interactions, namely, (i) between two imidazo[2,1-b]thiazole fragments [interplanar distance = 3.351 (2) Å] and (ii) between an imidazo[2,1-b]thiazole fragment and the phenyl ring [interplanar distance = 3.410 (5) Å]. There are no short contacts between the columns. International Union of Crystallography 2013-10-26 /pmc/articles/PMC3884351/ /pubmed/24454127 http://dx.doi.org/10.1107/S1600536813028833 Text en © Bunev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bunev, Alexander S. Sukhonosova, Elena V. Statsyuk, Vladimir E. Ostapenko, Gennady I. Khrustalev, Victor N. 6-(4-Chlorophenyl)-3-methylimidazo[2,1-b]thiazole |
title | 6-(4-Chlorophenyl)-3-methylimidazo[2,1-b]thiazole |
title_full | 6-(4-Chlorophenyl)-3-methylimidazo[2,1-b]thiazole |
title_fullStr | 6-(4-Chlorophenyl)-3-methylimidazo[2,1-b]thiazole |
title_full_unstemmed | 6-(4-Chlorophenyl)-3-methylimidazo[2,1-b]thiazole |
title_short | 6-(4-Chlorophenyl)-3-methylimidazo[2,1-b]thiazole |
title_sort | 6-(4-chlorophenyl)-3-methylimidazo[2,1-b]thiazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884351/ https://www.ncbi.nlm.nih.gov/pubmed/24454127 http://dx.doi.org/10.1107/S1600536813028833 |
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