2-[4-(Tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid

In the title compound, C(14)H(9)F(3)O(2)S, the dihedral angle between the mean planes of the benzene rings is 88.7 (2)°. The carb­oxy­lic acid group is twisted by 13.6 (7)° from the mean plane of its attached aromatic ring. One of the F atoms of the tri­fluoro­methyl group is disordered over two sit...

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Autores principales: Yamuna, Thammarse S., Jasinski, Jerry P., Anderson, Brian J., Yathirajan, H.S., Kaur, Manpreet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884354/
https://www.ncbi.nlm.nih.gov/pubmed/24454130
http://dx.doi.org/10.1107/S1600536813028778
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author Yamuna, Thammarse S.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H.S.
Kaur, Manpreet
author_facet Yamuna, Thammarse S.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H.S.
Kaur, Manpreet
author_sort Yamuna, Thammarse S.
collection PubMed
description In the title compound, C(14)H(9)F(3)O(2)S, the dihedral angle between the mean planes of the benzene rings is 88.7 (2)°. The carb­oxy­lic acid group is twisted by 13.6 (7)° from the mean plane of its attached aromatic ring. One of the F atoms of the tri­fluoro­methyl group is disordered over two sites in a 0.61 (7):0.39 (7) ratio. In the crystal, inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Weak C—H⋯F inter­actions are also observed.
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spelling pubmed-38843542014-01-17 2-[4-(Tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid Yamuna, Thammarse S. Jasinski, Jerry P. Anderson, Brian J. Yathirajan, H.S. Kaur, Manpreet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(9)F(3)O(2)S, the dihedral angle between the mean planes of the benzene rings is 88.7 (2)°. The carb­oxy­lic acid group is twisted by 13.6 (7)° from the mean plane of its attached aromatic ring. One of the F atoms of the tri­fluoro­methyl group is disordered over two sites in a 0.61 (7):0.39 (7) ratio. In the crystal, inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Weak C—H⋯F inter­actions are also observed. International Union of Crystallography 2013-10-26 /pmc/articles/PMC3884354/ /pubmed/24454130 http://dx.doi.org/10.1107/S1600536813028778 Text en © Yamuna et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamuna, Thammarse S.
Jasinski, Jerry P.
Anderson, Brian J.
Yathirajan, H.S.
Kaur, Manpreet
2-[4-(Tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid
title 2-[4-(Tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid
title_full 2-[4-(Tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid
title_fullStr 2-[4-(Tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid
title_full_unstemmed 2-[4-(Tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid
title_short 2-[4-(Tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid
title_sort 2-[4-(tri­fluoro­meth­yl)phenyl­sulfan­yl]benzoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884354/
https://www.ncbi.nlm.nih.gov/pubmed/24454130
http://dx.doi.org/10.1107/S1600536813028778
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AT kaurmanpreet 24trifluoromethylphenylsulfanylbenzoicacid

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