N-(2-Chloro­acet­yl)glycine

The title compound, C(4)H(6)ClNO(3), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. In each mol­ecule, there are N—H⋯O and N—H⋯Cl hydrogen bonds. Both mol­ecules are relatively planar, with the mean plane of the acetamide [N—C(=O)C] group being inclined to the mean pl...

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Detalles Bibliográficos
Autores principales: Zhang, Yu-Cheng, Zhang, Xiu-Qin, Wang, Kai, Chen, Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884360/
https://www.ncbi.nlm.nih.gov/pubmed/24454136
http://dx.doi.org/10.1107/S1600536813028997
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author Zhang, Yu-Cheng
Zhang, Xiu-Qin
Wang, Kai
Chen, Qiang
author_facet Zhang, Yu-Cheng
Zhang, Xiu-Qin
Wang, Kai
Chen, Qiang
author_sort Zhang, Yu-Cheng
collection PubMed
description The title compound, C(4)H(6)ClNO(3), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. In each mol­ecule, there are N—H⋯O and N—H⋯Cl hydrogen bonds. Both mol­ecules are relatively planar, with the mean plane of the acetamide [N—C(=O)C] group being inclined to the mean plane of the acetate group [C—C(=O)O] by 9.23 (13)° in mol­ecule A and 6.23 (12)° in mol­ecule B. In the crystal, adjacent mol­ecules are linked by O—H⋯O hydrogen bonds and weak C—H⋯O contacts forming –A–A–A– and –B–B–B– parallel chains propagating along the a-axis direction.
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spelling pubmed-38843602014-01-17 N-(2-Chloro­acet­yl)glycine Zhang, Yu-Cheng Zhang, Xiu-Qin Wang, Kai Chen, Qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(4)H(6)ClNO(3), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. In each mol­ecule, there are N—H⋯O and N—H⋯Cl hydrogen bonds. Both mol­ecules are relatively planar, with the mean plane of the acetamide [N—C(=O)C] group being inclined to the mean plane of the acetate group [C—C(=O)O] by 9.23 (13)° in mol­ecule A and 6.23 (12)° in mol­ecule B. In the crystal, adjacent mol­ecules are linked by O—H⋯O hydrogen bonds and weak C—H⋯O contacts forming –A–A–A– and –B–B–B– parallel chains propagating along the a-axis direction. International Union of Crystallography 2013-10-26 /pmc/articles/PMC3884360/ /pubmed/24454136 http://dx.doi.org/10.1107/S1600536813028997 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Yu-Cheng
Zhang, Xiu-Qin
Wang, Kai
Chen, Qiang
N-(2-Chloro­acet­yl)glycine
title N-(2-Chloro­acet­yl)glycine
title_full N-(2-Chloro­acet­yl)glycine
title_fullStr N-(2-Chloro­acet­yl)glycine
title_full_unstemmed N-(2-Chloro­acet­yl)glycine
title_short N-(2-Chloro­acet­yl)glycine
title_sort n-(2-chloro­acet­yl)glycine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884360/
https://www.ncbi.nlm.nih.gov/pubmed/24454136
http://dx.doi.org/10.1107/S1600536813028997
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AT zhangxiuqin n2chloroacetylglycine
AT wangkai n2chloroacetylglycine
AT chenqiang n2chloroacetylglycine

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