N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate

In the crystal structure of the title salt, C(16)H(36)N(+)·CH(3)BN(−), the tetra-n-butyl­ammonium cations and [BH(3)(CN)](−) anions are connected via weak C—H⋯N inter­actions, forming chains along the b-axis direction. The anion is almost linear with an N—C—B angle of 178.7 (2)°. The C—N—C angle val...

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Detalles Bibliográficos
Autor principal: Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884361/
https://www.ncbi.nlm.nih.gov/pubmed/24454137
http://dx.doi.org/10.1107/S1600536813028924
Descripción
Sumario:In the crystal structure of the title salt, C(16)H(36)N(+)·CH(3)BN(−), the tetra-n-butyl­ammonium cations and [BH(3)(CN)](−) anions are connected via weak C—H⋯N inter­actions, forming chains along the b-axis direction. The anion is almost linear with an N—C—B angle of 178.7 (2)°. The C—N—C angle values at the core of the tetra-n-butyl­ammonium cation range from 105.74 (11) to 111.35 (11)° with an average of 109.49 (11)°, close to the ideal tetra­hedral value.

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