N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate

In the crystal structure of the title salt, C(16)H(36)N(+)·CH(3)BN(−), the tetra-n-butyl­ammonium cations and [BH(3)(CN)](−) anions are connected via weak C—H⋯N inter­actions, forming chains along the b-axis direction. The anion is almost linear with an N—C—B angle of 178.7 (2)°. The C—N—C angle val...

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Autor principal: Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884361/
https://www.ncbi.nlm.nih.gov/pubmed/24454137
http://dx.doi.org/10.1107/S1600536813028924
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author Maris, Thierry
author_facet Maris, Thierry
author_sort Maris, Thierry
collection PubMed
description In the crystal structure of the title salt, C(16)H(36)N(+)·CH(3)BN(−), the tetra-n-butyl­ammonium cations and [BH(3)(CN)](−) anions are connected via weak C—H⋯N inter­actions, forming chains along the b-axis direction. The anion is almost linear with an N—C—B angle of 178.7 (2)°. The C—N—C angle values at the core of the tetra-n-butyl­ammonium cation range from 105.74 (11) to 111.35 (11)° with an average of 109.49 (11)°, close to the ideal tetra­hedral value.
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spelling pubmed-38843612014-01-17 N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate Maris, Thierry Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title salt, C(16)H(36)N(+)·CH(3)BN(−), the tetra-n-butyl­ammonium cations and [BH(3)(CN)](−) anions are connected via weak C—H⋯N inter­actions, forming chains along the b-axis direction. The anion is almost linear with an N—C—B angle of 178.7 (2)°. The C—N—C angle values at the core of the tetra-n-butyl­ammonium cation range from 105.74 (11) to 111.35 (11)° with an average of 109.49 (11)°, close to the ideal tetra­hedral value. International Union of Crystallography 2013-10-26 /pmc/articles/PMC3884361/ /pubmed/24454137 http://dx.doi.org/10.1107/S1600536813028924 Text en © Thierry Maris 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Maris, Thierry
N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate
title N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate
title_full N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate
title_fullStr N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate
title_full_unstemmed N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate
title_short N,N,N-Tri­butyl­butan-1-aminium (T-4)-(cyano-κC)tri­hydro­borate
title_sort n,n,n-tri­butyl­butan-1-aminium (t-4)-(cyano-κc)tri­hydro­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884361/
https://www.ncbi.nlm.nih.gov/pubmed/24454137
http://dx.doi.org/10.1107/S1600536813028924
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