Uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate

In the title compound, CH(5)N(2)O(+)·C(7)H(5)O(6)S(−), the dihedral angle between the benzene ring and the mean plane of the uronium cation is 76.02 (8)°. The carboxyl group in the anion is twisted by 1.47 (9)° from the benzene ring. In the crystal, the cation is linked to the anion by weak O—H⋯O an...

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Autores principales: Silambarasan, A., Kumar, M. Krishna, Chakkaravarthi, G., Kumar, R. Mohan, Umarani, P. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884371/
https://www.ncbi.nlm.nih.gov/pubmed/24454147
http://dx.doi.org/10.1107/S1600536813029474
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author Silambarasan, A.
Kumar, M. Krishna
Chakkaravarthi, G.
Kumar, R. Mohan
Umarani, P. R.
author_facet Silambarasan, A.
Kumar, M. Krishna
Chakkaravarthi, G.
Kumar, R. Mohan
Umarani, P. R.
author_sort Silambarasan, A.
collection PubMed
description In the title compound, CH(5)N(2)O(+)·C(7)H(5)O(6)S(−), the dihedral angle between the benzene ring and the mean plane of the uronium cation is 76.02 (8)°. The carboxyl group in the anion is twisted by 1.47 (9)° from the benzene ring. In the crystal, the cation is linked to the anion by weak O—H⋯O and N—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.8859 (8) Å], forming a three-dimensional network.
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spelling pubmed-38843712014-01-17 Uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate Silambarasan, A. Kumar, M. Krishna Chakkaravarthi, G. Kumar, R. Mohan Umarani, P. R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, CH(5)N(2)O(+)·C(7)H(5)O(6)S(−), the dihedral angle between the benzene ring and the mean plane of the uronium cation is 76.02 (8)°. The carboxyl group in the anion is twisted by 1.47 (9)° from the benzene ring. In the crystal, the cation is linked to the anion by weak O—H⋯O and N—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.8859 (8) Å], forming a three-dimensional network. International Union of Crystallography 2013-10-31 /pmc/articles/PMC3884371/ /pubmed/24454147 http://dx.doi.org/10.1107/S1600536813029474 Text en © Silambarasan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Silambarasan, A.
Kumar, M. Krishna
Chakkaravarthi, G.
Kumar, R. Mohan
Umarani, P. R.
Uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title Uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_full Uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_fullStr Uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_full_unstemmed Uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_short Uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
title_sort uronium 3-carb­oxy-4-hy­droxy­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884371/
https://www.ncbi.nlm.nih.gov/pubmed/24454147
http://dx.doi.org/10.1107/S1600536813029474
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AT kumarmkrishna uronium3carboxy4hydroxybenzenesulfonate
AT chakkaravarthig uronium3carboxy4hydroxybenzenesulfonate
AT kumarrmohan uronium3carboxy4hydroxybenzenesulfonate
AT umaranipr uronium3carboxy4hydroxybenzenesulfonate

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