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(Z)-N-(2,6-Diisopropylphenyl)-4-nitrobenzimidoyl chloride
In the title compound, C(19)H(21)ClN(2)O(2), the aromatic rings are approximately perpendicular to each other, subtending a dihedral angle of 87.7 (1)°. In the crystal, the 4-nitrophenyl groups of pairs of neighbouring molecules are parallel and oriented head-to-tail with a ring centroid–centroid...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884373/ https://www.ncbi.nlm.nih.gov/pubmed/24427026 http://dx.doi.org/10.1107/S1600536813020862 |
Sumario: | In the title compound, C(19)H(21)ClN(2)O(2), the aromatic rings are approximately perpendicular to each other, subtending a dihedral angle of 87.7 (1)°. In the crystal, the 4-nitrophenyl groups of pairs of neighbouring molecules are parallel and oriented head-to-tail with a ring centroid–centroid distance of 3.9247 (12) Å, leading to a π–π interaction between the pair. The faces of each phenyl ring of the 2,6-diisopropylphenyl group interact with two different groups, viz. a chloro group of an adjacent molecule on one side and the edge of the 4-nitrophenyl ring of a second molecule on the other side. |
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