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Diaquatetrakis(1H-imidazole-κN (3))magnesium dichloride
In the title compound, [Mg(C(3)H(3)N(2))(4)(H(2)O)(2)]Cl(2), the Mg(II) cation lies on a crystallographic inversion centre and is coordinated by two water molecules and four N-atom donors from monodentate imidazole ligands, giving a slightly distorted octahedral stereochemistry. In the crystal, wa...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884374/ https://www.ncbi.nlm.nih.gov/pubmed/24426982 http://dx.doi.org/10.1107/S1600536813021478 |
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author | Kayalvizhi, M. Vasuki, G. Kaabi, Kamel Ben Nasr, Cherif |
author_facet | Kayalvizhi, M. Vasuki, G. Kaabi, Kamel Ben Nasr, Cherif |
author_sort | Kayalvizhi, M. |
collection | PubMed |
description | In the title compound, [Mg(C(3)H(3)N(2))(4)(H(2)O)(2)]Cl(2), the Mg(II) cation lies on a crystallographic inversion centre and is coordinated by two water molecules and four N-atom donors from monodentate imidazole ligands, giving a slightly distorted octahedral stereochemistry. In the crystal, water O—H⋯Cl and imidazole N—H⋯Cl hydrogen bonds give rise to a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3884374 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38843742014-01-14 Diaquatetrakis(1H-imidazole-κN (3))magnesium dichloride Kayalvizhi, M. Vasuki, G. Kaabi, Kamel Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mg(C(3)H(3)N(2))(4)(H(2)O)(2)]Cl(2), the Mg(II) cation lies on a crystallographic inversion centre and is coordinated by two water molecules and four N-atom donors from monodentate imidazole ligands, giving a slightly distorted octahedral stereochemistry. In the crystal, water O—H⋯Cl and imidazole N—H⋯Cl hydrogen bonds give rise to a three-dimensional structure. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884374/ /pubmed/24426982 http://dx.doi.org/10.1107/S1600536813021478 Text en © Kayalvizhi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kayalvizhi, M. Vasuki, G. Kaabi, Kamel Ben Nasr, Cherif Diaquatetrakis(1H-imidazole-κN (3))magnesium dichloride |
title | Diaquatetrakis(1H-imidazole-κN
(3))magnesium dichloride |
title_full | Diaquatetrakis(1H-imidazole-κN
(3))magnesium dichloride |
title_fullStr | Diaquatetrakis(1H-imidazole-κN
(3))magnesium dichloride |
title_full_unstemmed | Diaquatetrakis(1H-imidazole-κN
(3))magnesium dichloride |
title_short | Diaquatetrakis(1H-imidazole-κN
(3))magnesium dichloride |
title_sort | diaquatetrakis(1h-imidazole-κn
(3))magnesium dichloride |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884374/ https://www.ncbi.nlm.nih.gov/pubmed/24426982 http://dx.doi.org/10.1107/S1600536813021478 |
work_keys_str_mv | AT kayalvizhim diaquatetrakis1himidazolekn3magnesiumdichloride AT vasukig diaquatetrakis1himidazolekn3magnesiumdichloride AT kaabikamel diaquatetrakis1himidazolekn3magnesiumdichloride AT bennasrcherif diaquatetrakis1himidazolekn3magnesiumdichloride |