Li(0.5)Al(0.5)Mg(2)(MoO(4))(3)

The title compound, lithium/aluminium dimagnesium tetra­kis­[orthomolybdate(VI)], was prepared by a solid-state reaction route. The crystal structure is built up from MgO(6) octa­hedra and MoO(4) tetra­hedra sharing corners and edges, forming two types of chains running along [100]. These chains are...

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Detalles Bibliográficos
Autores principales: Ennajeh, Ines, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884375/
https://www.ncbi.nlm.nih.gov/pubmed/24426975
http://dx.doi.org/10.1107/S1600536813022046
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author Ennajeh, Ines
Zid, Mohamed Faouzi
Driss, Ahmed
author_facet Ennajeh, Ines
Zid, Mohamed Faouzi
Driss, Ahmed
author_sort Ennajeh, Ines
collection PubMed
description The title compound, lithium/aluminium dimagnesium tetra­kis­[orthomolybdate(VI)], was prepared by a solid-state reaction route. The crystal structure is built up from MgO(6) octa­hedra and MoO(4) tetra­hedra sharing corners and edges, forming two types of chains running along [100]. These chains are linked into layers parallel to (010) and finally linked by MoO(4) tetra­hedra into a three-dimensional framework structure with channels parallel to [001] in which lithium and aluminium cations equally occupy the same position within a distorted trigonal–bipyramidal coordination environment. The title structure is isotypic with LiMgIn(MoO(4))(3), with the In site becoming an Mg site and the fully occupied Li site a statistically occupied Li/Al site in the title structure.
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spelling pubmed-38843752014-01-14 Li(0.5)Al(0.5)Mg(2)(MoO(4))(3) Ennajeh, Ines Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, lithium/aluminium dimagnesium tetra­kis­[orthomolybdate(VI)], was prepared by a solid-state reaction route. The crystal structure is built up from MgO(6) octa­hedra and MoO(4) tetra­hedra sharing corners and edges, forming two types of chains running along [100]. These chains are linked into layers parallel to (010) and finally linked by MoO(4) tetra­hedra into a three-dimensional framework structure with channels parallel to [001] in which lithium and aluminium cations equally occupy the same position within a distorted trigonal–bipyramidal coordination environment. The title structure is isotypic with LiMgIn(MoO(4))(3), with the In site becoming an Mg site and the fully occupied Li site a statistically occupied Li/Al site in the title structure. International Union of Crystallography 2013-08-14 /pmc/articles/PMC3884375/ /pubmed/24426975 http://dx.doi.org/10.1107/S1600536813022046 Text en © Ennajeh et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Ennajeh, Ines
Zid, Mohamed Faouzi
Driss, Ahmed
Li(0.5)Al(0.5)Mg(2)(MoO(4))(3)
title Li(0.5)Al(0.5)Mg(2)(MoO(4))(3)
title_full Li(0.5)Al(0.5)Mg(2)(MoO(4))(3)
title_fullStr Li(0.5)Al(0.5)Mg(2)(MoO(4))(3)
title_full_unstemmed Li(0.5)Al(0.5)Mg(2)(MoO(4))(3)
title_short Li(0.5)Al(0.5)Mg(2)(MoO(4))(3)
title_sort li(0.5)al(0.5)mg(2)(moo(4))(3)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884375/
https://www.ncbi.nlm.nih.gov/pubmed/24426975
http://dx.doi.org/10.1107/S1600536813022046
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