1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)

In the title salt, (C(12)H(20)N(2))[CuCl(4)], the Cu(II) atom occupies a general position in a flattened tetra­hedral environment by Cl ligands, characterized by Cl—Cu—Cl angles of 134.04 (3) and 137.18 (4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and i...

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Detalles Bibliográficos
Autores principales: Ben Mabrouk, Safa, Ameur, Iness, Abid, Sonia, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884381/
https://www.ncbi.nlm.nih.gov/pubmed/24426985
http://dx.doi.org/10.1107/S1600536813021454
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author Ben Mabrouk, Safa
Ameur, Iness
Abid, Sonia
Rzaigui, Mohamed
author_facet Ben Mabrouk, Safa
Ameur, Iness
Abid, Sonia
Rzaigui, Mohamed
author_sort Ben Mabrouk, Safa
collection PubMed
description In the title salt, (C(12)H(20)N(2))[CuCl(4)], the Cu(II) atom occupies a general position in a flattened tetra­hedral environment by Cl ligands, characterized by Cl—Cu—Cl angles of 134.04 (3) and 137.18 (4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and inorganic anion inter­act through N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-38843812014-01-14 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II) Ben Mabrouk, Safa Ameur, Iness Abid, Sonia Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(12)H(20)N(2))[CuCl(4)], the Cu(II) atom occupies a general position in a flattened tetra­hedral environment by Cl ligands, characterized by Cl—Cu—Cl angles of 134.04 (3) and 137.18 (4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and inorganic anion inter­act through N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884381/ /pubmed/24426985 http://dx.doi.org/10.1107/S1600536813021454 Text en © Ben Mabrouk et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ben Mabrouk, Safa
Ameur, Iness
Abid, Sonia
Rzaigui, Mohamed
1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_full 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_fullStr 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_full_unstemmed 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_short 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_sort 1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884381/
https://www.ncbi.nlm.nih.gov/pubmed/24426985
http://dx.doi.org/10.1107/S1600536813021454
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