2,5-Bis{[(–)-(S)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene

The title chiral bis-aldimine, C(24)H(26)N(2)S, was synthesized using a solvent-free Schiff condensation. The mol­ecule displays crystallographic C (2) symmetry, with the S atom lying on the twofold axis parallel to [100]. As a consequence of the (S,S) stereochemistry, the tolyl groups are oriented...

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Detalles Bibliográficos
Autores principales: Bernès, Sylvain, Hernández-Téllez, Guadalupe, Sharma, Manju, Portillo-Moreno, Oscar, Gutiérrez, René
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884388/
https://www.ncbi.nlm.nih.gov/pubmed/24427060
http://dx.doi.org/10.1107/S1600536813021685
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author Bernès, Sylvain
Hernández-Téllez, Guadalupe
Sharma, Manju
Portillo-Moreno, Oscar
Gutiérrez, René
author_facet Bernès, Sylvain
Hernández-Téllez, Guadalupe
Sharma, Manju
Portillo-Moreno, Oscar
Gutiérrez, René
author_sort Bernès, Sylvain
collection PubMed
description The title chiral bis-aldimine, C(24)H(26)N(2)S, was synthesized using a solvent-free Schiff condensation. The mol­ecule displays crystallographic C (2) symmetry, with the S atom lying on the twofold axis parallel to [100]. As a consequence of the (S,S) stereochemistry, the tolyl groups are oriented towards opposite faces of the thiophene core, giving a twisted conformation for the whole mol­ecule. Mol­ecules are arranged in the crystal in a herringbone-like pattern, without any significant inter­molecular contacts.
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spelling pubmed-38843882014-01-14 2,5-Bis{[(–)-(S)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene Bernès, Sylvain Hernández-Téllez, Guadalupe Sharma, Manju Portillo-Moreno, Oscar Gutiérrez, René Acta Crystallogr Sect E Struct Rep Online Organic Papers The title chiral bis-aldimine, C(24)H(26)N(2)S, was synthesized using a solvent-free Schiff condensation. The mol­ecule displays crystallographic C (2) symmetry, with the S atom lying on the twofold axis parallel to [100]. As a consequence of the (S,S) stereochemistry, the tolyl groups are oriented towards opposite faces of the thiophene core, giving a twisted conformation for the whole mol­ecule. Mol­ecules are arranged in the crystal in a herringbone-like pattern, without any significant inter­molecular contacts. International Union of Crystallography 2013-08-14 /pmc/articles/PMC3884388/ /pubmed/24427060 http://dx.doi.org/10.1107/S1600536813021685 Text en © Bernès et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bernès, Sylvain
Hernández-Téllez, Guadalupe
Sharma, Manju
Portillo-Moreno, Oscar
Gutiérrez, René
2,5-Bis{[(–)-(S)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene
title 2,5-Bis{[(–)-(S)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_full 2,5-Bis{[(–)-(S)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_fullStr 2,5-Bis{[(–)-(S)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_full_unstemmed 2,5-Bis{[(–)-(S)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_short 2,5-Bis{[(–)-(S)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_sort 2,5-bis{[(–)-(s)-1-(4-methyl­phen­yl)eth­yl]imino­meth­yl}thio­phene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884388/
https://www.ncbi.nlm.nih.gov/pubmed/24427060
http://dx.doi.org/10.1107/S1600536813021685
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