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Triphenyl(pyrrolidine-1-carbodithioato-κS)tin(IV)
In the title compound, [Sn(C(6)H(5))(3)(C(5)H(8)NS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetrahedral coordination geometry [spread of bond angles = 94.43 (7)–120.74 (7)°]. A short intramolecular Sn⋯S contact [3.0270 (9) Å] occurs and two intramolecular C—H⋯S interactions help to estab...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884390/ https://www.ncbi.nlm.nih.gov/pubmed/24426993 http://dx.doi.org/10.1107/S1600536813022472 |
Sumario: | In the title compound, [Sn(C(6)H(5))(3)(C(5)H(8)NS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetrahedral coordination geometry [spread of bond angles = 94.43 (7)–120.74 (7)°]. A short intramolecular Sn⋯S contact [3.0270 (9) Å] occurs and two intramolecular C—H⋯S interactions help to establish the conformation. Three of the methylene groups of the pyrrolidine-1-carbodithioate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C—H⋯S interactions link the molecules into a three-dimensional network, with both S atoms acting as acceptors. |
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