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Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV)

In the title compound, [Sn(C(6)H(5))(3)(C(5)H(8)NS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetra­hedral coordination geometry [spread of bond angles = 94.43 (7)–120.74 (7)°]. A short intra­molecular Sn⋯S contact [3.0270 (9) Å] occurs and two intra­molecular C—H⋯S inter­actions help to estab...

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Detalles Bibliográficos
Autores principales: Sirajuddin, Muhammad, Uddin, Noor, Ali, Saqib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884390/
https://www.ncbi.nlm.nih.gov/pubmed/24426993
http://dx.doi.org/10.1107/S1600536813022472
Descripción
Sumario:In the title compound, [Sn(C(6)H(5))(3)(C(5)H(8)NS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetra­hedral coordination geometry [spread of bond angles = 94.43 (7)–120.74 (7)°]. A short intra­molecular Sn⋯S contact [3.0270 (9) Å] occurs and two intra­molecular C—H⋯S inter­actions help to establish the conformation. Three of the methyl­ene groups of the pyrrolidine-1-carbodi­thio­ate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C—H⋯S inter­actions link the mol­ecules into a three-dimensional network, with both S atoms acting as acceptors.