Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV)

In the title compound, [Sn(C(6)H(5))(3)(C(5)H(8)NS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetra­hedral coordination geometry [spread of bond angles = 94.43 (7)–120.74 (7)°]. A short intra­molecular Sn⋯S contact [3.0270 (9) Å] occurs and two intra­molecular C—H⋯S inter­actions help to estab...

Descripción completa

Detalles Bibliográficos
Autores principales: Sirajuddin, Muhammad, Uddin, Noor, Ali, Saqib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884390/
https://www.ncbi.nlm.nih.gov/pubmed/24426993
http://dx.doi.org/10.1107/S1600536813022472
_version_ 1782298579718635520
author Sirajuddin, Muhammad
Uddin, Noor
Ali, Saqib
author_facet Sirajuddin, Muhammad
Uddin, Noor
Ali, Saqib
author_sort Sirajuddin, Muhammad
collection PubMed
description In the title compound, [Sn(C(6)H(5))(3)(C(5)H(8)NS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetra­hedral coordination geometry [spread of bond angles = 94.43 (7)–120.74 (7)°]. A short intra­molecular Sn⋯S contact [3.0270 (9) Å] occurs and two intra­molecular C—H⋯S inter­actions help to establish the conformation. Three of the methyl­ene groups of the pyrrolidine-1-carbodi­thio­ate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C—H⋯S inter­actions link the mol­ecules into a three-dimensional network, with both S atoms acting as acceptors.
format Online
Article
Text
id pubmed-3884390
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38843902014-01-14 Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV) Sirajuddin, Muhammad Uddin, Noor Ali, Saqib Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(6)H(5))(3)(C(5)H(8)NS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetra­hedral coordination geometry [spread of bond angles = 94.43 (7)–120.74 (7)°]. A short intra­molecular Sn⋯S contact [3.0270 (9) Å] occurs and two intra­molecular C—H⋯S inter­actions help to establish the conformation. Three of the methyl­ene groups of the pyrrolidine-1-carbodi­thio­ate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C—H⋯S inter­actions link the mol­ecules into a three-dimensional network, with both S atoms acting as acceptors. International Union of Crystallography 2013-08-17 /pmc/articles/PMC3884390/ /pubmed/24426993 http://dx.doi.org/10.1107/S1600536813022472 Text en © Sirajuddin et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sirajuddin, Muhammad
Uddin, Noor
Ali, Saqib
Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV)
title Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV)
title_full Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV)
title_fullStr Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV)
title_full_unstemmed Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV)
title_short Triphen­yl(pyrrolidine-1-carbodi­thio­ato-κS)tin(IV)
title_sort triphen­yl(pyrrolidine-1-carbodi­thio­ato-κs)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884390/
https://www.ncbi.nlm.nih.gov/pubmed/24426993
http://dx.doi.org/10.1107/S1600536813022472
work_keys_str_mv AT sirajuddinmuhammad triphenylpyrrolidine1carbodithioatokstiniv
AT uddinnoor triphenylpyrrolidine1carbodithioatokstiniv
AT alisaqib triphenylpyrrolidine1carbodithioatokstiniv

Ejemplares similares