1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one

In the title compound, C(17)H(16)N(2)O, the fused benzimidazol-2(3H)-one system is essentially planar, the largest deviation from the mean plane being 0.006 (2) Å for the carbonyl C atom. Its mean plane is almost perpendicular to the benzyl plane and to the allyl group, making dihedral angles of 80....

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Autores principales: Kandri Rodi, Youssef, Haoudi, Amal, Capet, Frédéric, Mazzah, Ahmed, Essassi, El Mokhtar, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884391/
https://www.ncbi.nlm.nih.gov/pubmed/24427099
http://dx.doi.org/10.1107/S1600536813023568
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author Kandri Rodi, Youssef
Haoudi, Amal
Capet, Frédéric
Mazzah, Ahmed
Essassi, El Mokhtar
El Ammari, Lahcen
author_facet Kandri Rodi, Youssef
Haoudi, Amal
Capet, Frédéric
Mazzah, Ahmed
Essassi, El Mokhtar
El Ammari, Lahcen
author_sort Kandri Rodi, Youssef
collection PubMed
description In the title compound, C(17)H(16)N(2)O, the fused benzimidazol-2(3H)-one system is essentially planar, the largest deviation from the mean plane being 0.006 (2) Å for the carbonyl C atom. Its mean plane is almost perpendicular to the benzyl plane and to the allyl group, making dihedral angles of 80.6 (1) and 77.4 (3)°, respectively. The benzyl group and the allyl subsituent lie on opposite sides of the fused ring system. In the crystal, mol­ecules are linked by bifurcated C—H⋯O hydrogen bonds in which the carbonyl O atom acts as accepter to two aromatic C—H groups, forming a two-dimensional network parallel to (001).
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spelling pubmed-38843912014-01-14 1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one Kandri Rodi, Youssef Haoudi, Amal Capet, Frédéric Mazzah, Ahmed Essassi, El Mokhtar El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(16)N(2)O, the fused benzimidazol-2(3H)-one system is essentially planar, the largest deviation from the mean plane being 0.006 (2) Å for the carbonyl C atom. Its mean plane is almost perpendicular to the benzyl plane and to the allyl group, making dihedral angles of 80.6 (1) and 77.4 (3)°, respectively. The benzyl group and the allyl subsituent lie on opposite sides of the fused ring system. In the crystal, mol­ecules are linked by bifurcated C—H⋯O hydrogen bonds in which the carbonyl O atom acts as accepter to two aromatic C—H groups, forming a two-dimensional network parallel to (001). International Union of Crystallography 2013-08-31 /pmc/articles/PMC3884391/ /pubmed/24427099 http://dx.doi.org/10.1107/S1600536813023568 Text en © Kandri Rodi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kandri Rodi, Youssef
Haoudi, Amal
Capet, Frédéric
Mazzah, Ahmed
Essassi, El Mokhtar
El Ammari, Lahcen
1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one
title 1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one
title_full 1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one
title_fullStr 1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one
title_full_unstemmed 1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one
title_short 1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one
title_sort 1-allyl-3-benzyl-1h-benzimidazol-2(3h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884391/
https://www.ncbi.nlm.nih.gov/pubmed/24427099
http://dx.doi.org/10.1107/S1600536813023568
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