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Bis[O,O′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) S,S′]bis­(pyridine-κN)lead(II)

In the title compound, [Pb(C(20)H(26)O(2)PS(2))(2)(C(5)H(5)N)(2)], the Pb(II) ion is coordinated by two S,S′-bidentate anions and two pyridine mol­ecules. The PbN(2)S(4) coordination geometry approximates to a penta­gonal bipyramid with one equatorial site vacant. The N atoms occupy the axial sites....

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Detalles Bibliográficos
Autores principales: Zhang, Xiulan, Xie, Bin, He, Linxin, Lu, Lu, Chen, Neng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884392/
https://www.ncbi.nlm.nih.gov/pubmed/24427011
http://dx.doi.org/10.1107/S1600536813023945
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author Zhang, Xiulan
Xie, Bin
He, Linxin
Lu, Lu
Chen, Neng
author_facet Zhang, Xiulan
Xie, Bin
He, Linxin
Lu, Lu
Chen, Neng
author_sort Zhang, Xiulan
collection PubMed
description In the title compound, [Pb(C(20)H(26)O(2)PS(2))(2)(C(5)H(5)N)(2)], the Pb(II) ion is coordinated by two S,S′-bidentate anions and two pyridine mol­ecules. The PbN(2)S(4) coordination geometry approximates to a penta­gonal bipyramid with one equatorial site vacant. The N atoms occupy the axial sites. One of the pyridine mol­ecules is disordered over two sets of sites in a 0.907 (7):0.093 (7) ratio and one of the tert-butyl groups is disordered over two sets of sites in a 0.534 (6):0.466 (6) ratio. An intra­molecular C—H⋯O inter­action occurs in one of the ligands. In the crystal, pairs of short Pb⋯S contacts [3.4018 (11) Å] generate a centrosymmetric dimeric assembly with the distant S atom lying in the region of the vacant coordination site of the metal atom. No directional packing inter­actions occur.
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spelling pubmed-38843922014-01-14 Bis[O,O′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) S,S′]bis­(pyridine-κN)lead(II) Zhang, Xiulan Xie, Bin He, Linxin Lu, Lu Chen, Neng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(C(20)H(26)O(2)PS(2))(2)(C(5)H(5)N)(2)], the Pb(II) ion is coordinated by two S,S′-bidentate anions and two pyridine mol­ecules. The PbN(2)S(4) coordination geometry approximates to a penta­gonal bipyramid with one equatorial site vacant. The N atoms occupy the axial sites. One of the pyridine mol­ecules is disordered over two sets of sites in a 0.907 (7):0.093 (7) ratio and one of the tert-butyl groups is disordered over two sets of sites in a 0.534 (6):0.466 (6) ratio. An intra­molecular C—H⋯O inter­action occurs in one of the ligands. In the crystal, pairs of short Pb⋯S contacts [3.4018 (11) Å] generate a centrosymmetric dimeric assembly with the distant S atom lying in the region of the vacant coordination site of the metal atom. No directional packing inter­actions occur. International Union of Crystallography 2013-08-31 /pmc/articles/PMC3884392/ /pubmed/24427011 http://dx.doi.org/10.1107/S1600536813023945 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiulan
Xie, Bin
He, Linxin
Lu, Lu
Chen, Neng
Bis[O,O′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) S,S′]bis­(pyridine-κN)lead(II)
title Bis[O,O′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) S,S′]bis­(pyridine-κN)lead(II)
title_full Bis[O,O′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) S,S′]bis­(pyridine-κN)lead(II)
title_fullStr Bis[O,O′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) S,S′]bis­(pyridine-κN)lead(II)
title_full_unstemmed Bis[O,O′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) S,S′]bis­(pyridine-κN)lead(II)
title_short Bis[O,O′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) S,S′]bis­(pyridine-κN)lead(II)
title_sort bis[o,o′-bis­(4-tert-butyl­phen­yl) di­thio­phosphato-κ(2) s,s′]bis­(pyridine-κn)lead(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884392/
https://www.ncbi.nlm.nih.gov/pubmed/24427011
http://dx.doi.org/10.1107/S1600536813023945
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