Cargando…
Di-μ-chlorido-dichloridobis{8-[2-(dimethylamino)ethylamino]quinoline}dicadmium monohydrate
The title complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·H(2)O, is centrosymmetic and contains two Cd(2+) ions bridged by two Cl(−) ions, leading to a strictly planar Cd(2)Cl(2) core. Each Cd(2+) ion is further coordinated by an additional Cl(−) ion and three N atoms of a tridentate 8-[2-(dimethylamino)...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884398/ https://www.ncbi.nlm.nih.gov/pubmed/24426990 http://dx.doi.org/10.1107/S160053681302206X |
Sumario: | The title complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·H(2)O, is centrosymmetic and contains two Cd(2+) ions bridged by two Cl(−) ions, leading to a strictly planar Cd(2)Cl(2) core. Each Cd(2+) ion is further coordinated by an additional Cl(−) ion and three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand in the form of a considerably distorted octahedron for the overall coordination sphere. A lattice water molecule is located on a twofold rotation axis and links pairs of complexes through N—H⋯O and O—H⋯Cl hydrogen bonds. |
---|