Di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate

The title complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·H(2)O, is centrosymmetic and contains two Cd(2+) ions bridged by two Cl(−) ions, leading to a strictly planar Cd(2)Cl(2) core. Each Cd(2+) ion is further coordinated by an additional Cl(−) ion and three N atoms of a tridentate 8-[2-(di­methyl­amino)...

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Detalles Bibliográficos
Autores principales: Al-Sudani, Abdul-Razak H., Kariuki, Benson M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884398/
https://www.ncbi.nlm.nih.gov/pubmed/24426990
http://dx.doi.org/10.1107/S160053681302206X
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author Al-Sudani, Abdul-Razak H.
Kariuki, Benson M.
author_facet Al-Sudani, Abdul-Razak H.
Kariuki, Benson M.
author_sort Al-Sudani, Abdul-Razak H.
collection PubMed
description The title complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·H(2)O, is centrosymmetic and contains two Cd(2+) ions bridged by two Cl(−) ions, leading to a strictly planar Cd(2)Cl(2) core. Each Cd(2+) ion is further coordinated by an additional Cl(−) ion and three N atoms of a tridentate 8-[2-(di­methyl­amino)­ethyl­amino]­quinoline ligand in the form of a considerably distorted octa­hedron for the overall coordination sphere. A lattice water mol­ecule is located on a twofold rotation axis and links pairs of complexes through N—H⋯O and O—H⋯Cl hydrogen bonds.
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spelling pubmed-38843982014-01-14 Di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate Al-Sudani, Abdul-Razak H. Kariuki, Benson M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·H(2)O, is centrosymmetic and contains two Cd(2+) ions bridged by two Cl(−) ions, leading to a strictly planar Cd(2)Cl(2) core. Each Cd(2+) ion is further coordinated by an additional Cl(−) ion and three N atoms of a tridentate 8-[2-(di­methyl­amino)­ethyl­amino]­quinoline ligand in the form of a considerably distorted octa­hedron for the overall coordination sphere. A lattice water mol­ecule is located on a twofold rotation axis and links pairs of complexes through N—H⋯O and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2013-08-14 /pmc/articles/PMC3884398/ /pubmed/24426990 http://dx.doi.org/10.1107/S160053681302206X Text en © Al-Sudani and Kariuki 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Al-Sudani, Abdul-Razak H.
Kariuki, Benson M.
Di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate
title Di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate
title_full Di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate
title_fullStr Di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate
title_full_unstemmed Di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate
title_short Di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate
title_sort di-μ-chlorido-dichlorido­bis{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}dicadmium monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884398/
https://www.ncbi.nlm.nih.gov/pubmed/24426990
http://dx.doi.org/10.1107/S160053681302206X
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