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2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl pyrrolidine-1-carbodi­thio­ate

There are two independent mol­ecules in the asymmetric unit of the title compound, C(16)H(15)NO(3)S(2), in which the pyrrolidine rings adopt envelope conformations, with a methyl­ene C atom as the flap. The dihedral angles betweeen the near-planar 2H-chromene ring systems [maximum deviations = 0.016...

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Detalles Bibliográficos
Autores principales: Kumar, K. Mahesh, Mahabhaleshwaraiah, N. M., Kotresh, O., Roopashree, K. R., Devarajegowda, H. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884401/
https://www.ncbi.nlm.nih.gov/pubmed/24427024
http://dx.doi.org/10.1107/S1600536813020965
Descripción
Sumario:There are two independent mol­ecules in the asymmetric unit of the title compound, C(16)H(15)NO(3)S(2), in which the pyrrolidine rings adopt envelope conformations, with a methyl­ene C atom as the flap. The dihedral angles betweeen the near-planar 2H-chromene ring systems [maximum deviations = 0.0167 (20) and 0.0136 (19) Å] and the pyrrolidine rings (all atoms) are 83.83 (11) and 82.43 (11)°. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds occur for one of the mol­ecules. Further C—H⋯O links involving both mol­ecules generate a three-dimensional network.