Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)]

The title compound, [Cu(2)Cl(4)(C(7)H(8)N(2)O)(2)], crystallizes as discrete [CuLCl(2)](2) (L = 2-amino­benzamide) dimers with inversion symmetry. Each Cu(II) ion is five-coordinated and is bound to two bridging chloride ligands, a terminal chloride ligand and a bidentate 2-amino­benzamide ligand. T...

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Detalles Bibliográficos
Autores principales: Damous, Maamar, Dénès, George, Bouacida, Sofiane, Hamlaoui, Meriem, Merazig, Hocine, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884402/
https://www.ncbi.nlm.nih.gov/pubmed/24426988
http://dx.doi.org/10.1107/S1600536813021879
Descripción
Sumario:The title compound, [Cu(2)Cl(4)(C(7)H(8)N(2)O)(2)], crystallizes as discrete [CuLCl(2)](2) (L = 2-amino­benzamide) dimers with inversion symmetry. Each Cu(II) ion is five-coordinated and is bound to two bridging chloride ligands, a terminal chloride ligand and a bidentate 2-amino­benzamide ligand. The crystal structure exhibits alternating layers parallel to (010) along the b-axis direction. In the crystal, the components are linked via N—H⋯Cl hydrogen bonds, forming a three-dimensional network. These inter­actions link the mol­ecules within the layers and also link the layers together and reinforce the cohesion of the structure.

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