Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)]

The title compound, [Cu(2)Cl(4)(C(7)H(8)N(2)O)(2)], crystallizes as discrete [CuLCl(2)](2) (L = 2-amino­benzamide) dimers with inversion symmetry. Each Cu(II) ion is five-coordinated and is bound to two bridging chloride ligands, a terminal chloride ligand and a bidentate 2-amino­benzamide ligand. T...

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Autores principales: Damous, Maamar, Dénès, George, Bouacida, Sofiane, Hamlaoui, Meriem, Merazig, Hocine, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884402/
https://www.ncbi.nlm.nih.gov/pubmed/24426988
http://dx.doi.org/10.1107/S1600536813021879
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author Damous, Maamar
Dénès, George
Bouacida, Sofiane
Hamlaoui, Meriem
Merazig, Hocine
Daran, Jean-Claude
author_facet Damous, Maamar
Dénès, George
Bouacida, Sofiane
Hamlaoui, Meriem
Merazig, Hocine
Daran, Jean-Claude
author_sort Damous, Maamar
collection PubMed
description The title compound, [Cu(2)Cl(4)(C(7)H(8)N(2)O)(2)], crystallizes as discrete [CuLCl(2)](2) (L = 2-amino­benzamide) dimers with inversion symmetry. Each Cu(II) ion is five-coordinated and is bound to two bridging chloride ligands, a terminal chloride ligand and a bidentate 2-amino­benzamide ligand. The crystal structure exhibits alternating layers parallel to (010) along the b-axis direction. In the crystal, the components are linked via N—H⋯Cl hydrogen bonds, forming a three-dimensional network. These inter­actions link the mol­ecules within the layers and also link the layers together and reinforce the cohesion of the structure.
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spelling pubmed-38844022014-01-14 Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)] Damous, Maamar Dénès, George Bouacida, Sofiane Hamlaoui, Meriem Merazig, Hocine Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)Cl(4)(C(7)H(8)N(2)O)(2)], crystallizes as discrete [CuLCl(2)](2) (L = 2-amino­benzamide) dimers with inversion symmetry. Each Cu(II) ion is five-coordinated and is bound to two bridging chloride ligands, a terminal chloride ligand and a bidentate 2-amino­benzamide ligand. The crystal structure exhibits alternating layers parallel to (010) along the b-axis direction. In the crystal, the components are linked via N—H⋯Cl hydrogen bonds, forming a three-dimensional network. These inter­actions link the mol­ecules within the layers and also link the layers together and reinforce the cohesion of the structure. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884402/ /pubmed/24426988 http://dx.doi.org/10.1107/S1600536813021879 Text en © Damous et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Damous, Maamar
Dénès, George
Bouacida, Sofiane
Hamlaoui, Meriem
Merazig, Hocine
Daran, Jean-Claude
Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)]
title Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)]
title_full Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)]
title_fullStr Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)]
title_full_unstemmed Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)]
title_short Di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) N (2),O)chlorido­copper(II)]
title_sort di-μ-chlorido-bis­[(2-amino­benzamide-κ(2) n (2),o)chlorido­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884402/
https://www.ncbi.nlm.nih.gov/pubmed/24426988
http://dx.doi.org/10.1107/S1600536813021879
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