Ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate

In the title compound, C(21)H(19)BrFNO(2), two independent mol­ecules crystallize in the asymmetric unit. The cyclo­hexa-1,3-diene ring is in a slightly distorted screw-boat conformation. The dihedral angles between the mean planes of the 4-bromo­phenyl and 4-fluoro­phenyl rings are 81.0 (3) and 76....

Descripción completa

Detalles Bibliográficos
Autores principales: Narayana, B., Sapnakumari, M., Jasinski, Jerry P., Fraiser, Peter M., Yathirajan, H. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884405/
https://www.ncbi.nlm.nih.gov/pubmed/24427095
http://dx.doi.org/10.1107/S1600536813023325
_version_ 1782298583104487424
author Narayana, B.
Sapnakumari, M.
Jasinski, Jerry P.
Fraiser, Peter M.
Yathirajan, H. S.
author_facet Narayana, B.
Sapnakumari, M.
Jasinski, Jerry P.
Fraiser, Peter M.
Yathirajan, H. S.
author_sort Narayana, B.
collection PubMed
description In the title compound, C(21)H(19)BrFNO(2), two independent mol­ecules crystallize in the asymmetric unit. The cyclo­hexa-1,3-diene ring is in a slightly distorted screw-boat conformation. The dihedral angles between the mean planes of the 4-bromo­phenyl and 4-fluoro­phenyl rings are 81.0 (3) and 76.4 (2)° in the two independent mol­ecules. In the crystal, N—H⋯O hydrogen bonds link the molecules into [100] chains.
format Online
Article
Text
id pubmed-3884405
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38844052014-01-14 Ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate Narayana, B. Sapnakumari, M. Jasinski, Jerry P. Fraiser, Peter M. Yathirajan, H. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(19)BrFNO(2), two independent mol­ecules crystallize in the asymmetric unit. The cyclo­hexa-1,3-diene ring is in a slightly distorted screw-boat conformation. The dihedral angles between the mean planes of the 4-bromo­phenyl and 4-fluoro­phenyl rings are 81.0 (3) and 76.4 (2)° in the two independent mol­ecules. In the crystal, N—H⋯O hydrogen bonds link the molecules into [100] chains. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884405/ /pubmed/24427095 http://dx.doi.org/10.1107/S1600536813023325 Text en © Narayana et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Narayana, B.
Sapnakumari, M.
Jasinski, Jerry P.
Fraiser, Peter M.
Yathirajan, H. S.
Ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate
title Ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate
title_full Ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate
title_fullStr Ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate
title_full_unstemmed Ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate
title_short Ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate
title_sort ethyl 2-amino-6-(4-bromo­phen­yl)-4-(4-fluoro­phen­yl)cyclo­hexa-1,3-diene-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884405/
https://www.ncbi.nlm.nih.gov/pubmed/24427095
http://dx.doi.org/10.1107/S1600536813023325
work_keys_str_mv AT narayanab ethyl2amino64bromophenyl44fluorophenylcyclohexa13diene1carboxylate
AT sapnakumarim ethyl2amino64bromophenyl44fluorophenylcyclohexa13diene1carboxylate
AT jasinskijerryp ethyl2amino64bromophenyl44fluorophenylcyclohexa13diene1carboxylate
AT fraiserpeterm ethyl2amino64bromophenyl44fluorophenylcyclohexa13diene1carboxylate
AT yathirajanhs ethyl2amino64bromophenyl44fluorophenylcyclohexa13diene1carboxylate

Ejemplares similares