Cargando…
4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole
In the title compound, C(14)H(21)N(3)O(5), the tetrahydrofuran ring adopts an envelope conformation with the C atom bearing the substituent as the flap. The pentafuranose ring adopts a twisted conformation about the C—C bond fusing the rings. The dihedral angle between these rings (all atoms), w...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884407/ https://www.ncbi.nlm.nih.gov/pubmed/24427028 http://dx.doi.org/10.1107/S1600536813021351 |
Sumario: | In the title compound, C(14)H(21)N(3)O(5), the tetrahydrofuran ring adopts an envelope conformation with the C atom bearing the substituent as the flap. The pentafuranose ring adopts a twisted conformation about the C—C bond fusing the rings. The dihedral angle between these rings (all atoms), which are cis fused, is 72.89 (14)°. The cyclopropane ring is disordered over two orientations in a 0.576 (5):0.424 (5) ratio; the dihedral angles subtended to the triazole ring are 53.3 (11) and 46.6 (9)°, respectively. In the crystal, the molecules are linked by O—H⋯N and O—H⋯O hydrogen bonds, generating (001) sheets. A weak C—H⋯O interaction also occurs. |
---|