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4-Cyclo­propyl-1-(6′-de­oxy-1′,2′-O-iso­propyl­idene-α-d-gluco­furanos­yl)-1H-1,2,3-triazole

In the title compound, C(14)H(21)N(3)O(5), the tetra­hydro­furan ring adopts an envelope conformation with the C atom bearing the substituent as the flap. The penta­furan­ose ring adopts a twisted conformation about the C—C bond fusing the rings. The dihedral angle between these rings (all atoms), w...

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Detalles Bibliográficos
Autores principales: Zhang, Qiurong, He, Peng, Zhou, Guangqiang, Yu, Kang, Liu, Hongmin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884407/
https://www.ncbi.nlm.nih.gov/pubmed/24427028
http://dx.doi.org/10.1107/S1600536813021351
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author Zhang, Qiurong
He, Peng
Zhou, Guangqiang
Yu, Kang
Liu, Hongmin
author_facet Zhang, Qiurong
He, Peng
Zhou, Guangqiang
Yu, Kang
Liu, Hongmin
author_sort Zhang, Qiurong
collection PubMed
description In the title compound, C(14)H(21)N(3)O(5), the tetra­hydro­furan ring adopts an envelope conformation with the C atom bearing the substituent as the flap. The penta­furan­ose ring adopts a twisted conformation about the C—C bond fusing the rings. The dihedral angle between these rings (all atoms), which are cis fused, is 72.89 (14)°. The cyclo­propane ring is disordered over two orientations in a 0.576 (5):0.424 (5) ratio; the dihedral angles subtended to the triazole ring are 53.3 (11) and 46.6 (9)°, respectively. In the crystal, the mol­ecules are linked by O—H⋯N and O—H⋯O hydrogen bonds, generating (001) sheets. A weak C—H⋯O inter­action also occurs.
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spelling pubmed-38844072014-01-14 4-Cyclo­propyl-1-(6′-de­oxy-1′,2′-O-iso­propyl­idene-α-d-gluco­furanos­yl)-1H-1,2,3-triazole Zhang, Qiurong He, Peng Zhou, Guangqiang Yu, Kang Liu, Hongmin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(21)N(3)O(5), the tetra­hydro­furan ring adopts an envelope conformation with the C atom bearing the substituent as the flap. The penta­furan­ose ring adopts a twisted conformation about the C—C bond fusing the rings. The dihedral angle between these rings (all atoms), which are cis fused, is 72.89 (14)°. The cyclo­propane ring is disordered over two orientations in a 0.576 (5):0.424 (5) ratio; the dihedral angles subtended to the triazole ring are 53.3 (11) and 46.6 (9)°, respectively. In the crystal, the mol­ecules are linked by O—H⋯N and O—H⋯O hydrogen bonds, generating (001) sheets. A weak C—H⋯O inter­action also occurs. International Union of Crystallography 2013-08-07 /pmc/articles/PMC3884407/ /pubmed/24427028 http://dx.doi.org/10.1107/S1600536813021351 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Qiurong
He, Peng
Zhou, Guangqiang
Yu, Kang
Liu, Hongmin
4-Cyclo­propyl-1-(6′-de­oxy-1′,2′-O-iso­propyl­idene-α-d-gluco­furanos­yl)-1H-1,2,3-triazole
title 4-Cyclo­propyl-1-(6′-de­oxy-1′,2′-O-iso­propyl­idene-α-d-gluco­furanos­yl)-1H-1,2,3-triazole
title_full 4-Cyclo­propyl-1-(6′-de­oxy-1′,2′-O-iso­propyl­idene-α-d-gluco­furanos­yl)-1H-1,2,3-triazole
title_fullStr 4-Cyclo­propyl-1-(6′-de­oxy-1′,2′-O-iso­propyl­idene-α-d-gluco­furanos­yl)-1H-1,2,3-triazole
title_full_unstemmed 4-Cyclo­propyl-1-(6′-de­oxy-1′,2′-O-iso­propyl­idene-α-d-gluco­furanos­yl)-1H-1,2,3-triazole
title_short 4-Cyclo­propyl-1-(6′-de­oxy-1′,2′-O-iso­propyl­idene-α-d-gluco­furanos­yl)-1H-1,2,3-triazole
title_sort 4-cyclo­propyl-1-(6′-de­oxy-1′,2′-o-iso­propyl­idene-α-d-gluco­furanos­yl)-1h-1,2,3-triazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884407/
https://www.ncbi.nlm.nih.gov/pubmed/24427028
http://dx.doi.org/10.1107/S1600536813021351
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