2-Isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one

The title compound, C(16)H(20)N(2)O(2)S(2), crystallizes with two enanti­omers (A and B) in the asymmetric unit. The most noticeable difference between these two mol­ecules is the relative orientation of the benzo­thia­zole rings, with S—C—C—S torsion angles of −19.4 (2) (mol­ecule A) and 100.6 (1)°...

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Detalles Bibliográficos
Autores principales: Würfel, Hendryk, Görls, Helmar, Weiss, Dieter, Beckert, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884408/
https://www.ncbi.nlm.nih.gov/pubmed/24427032
http://dx.doi.org/10.1107/S1600536813019521
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author Würfel, Hendryk
Görls, Helmar
Weiss, Dieter
Beckert, Rainer
author_facet Würfel, Hendryk
Görls, Helmar
Weiss, Dieter
Beckert, Rainer
author_sort Würfel, Hendryk
collection PubMed
description The title compound, C(16)H(20)N(2)O(2)S(2), crystallizes with two enanti­omers (A and B) in the asymmetric unit. The most noticeable difference between these two mol­ecules is the relative orientation of the benzo­thia­zole rings, with S—C—C—S torsion angles of −19.4 (2) (mol­ecule A) and 100.6 (1)° (mol­ecule B). The amide structure of the thia­zolidinone rings leads to inter­molecular hydrogen-bonded dimers of the R and S enanti­omers.
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spelling pubmed-38844082014-01-14 2-Isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one Würfel, Hendryk Görls, Helmar Weiss, Dieter Beckert, Rainer Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(20)N(2)O(2)S(2), crystallizes with two enanti­omers (A and B) in the asymmetric unit. The most noticeable difference between these two mol­ecules is the relative orientation of the benzo­thia­zole rings, with S—C—C—S torsion angles of −19.4 (2) (mol­ecule A) and 100.6 (1)° (mol­ecule B). The amide structure of the thia­zolidinone rings leads to inter­molecular hydrogen-bonded dimers of the R and S enanti­omers. International Union of Crystallography 2013-08-07 /pmc/articles/PMC3884408/ /pubmed/24427032 http://dx.doi.org/10.1107/S1600536813019521 Text en © Würfel et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Würfel, Hendryk
Görls, Helmar
Weiss, Dieter
Beckert, Rainer
2-Isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one
title 2-Isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one
title_full 2-Isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one
title_fullStr 2-Isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one
title_full_unstemmed 2-Isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one
title_short 2-Isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one
title_sort 2-isopropyl-2-(6-meth­oxy-1,3-benzo­thia­zol-2-yl)-5,5-dimethyl-1,3-thia­zolidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884408/
https://www.ncbi.nlm.nih.gov/pubmed/24427032
http://dx.doi.org/10.1107/S1600536813019521
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AT beckertrainer 2isopropyl26methoxy13benzothiazol2yl55dimethyl13thiazolidin4one

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