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Di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1H-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) N (3),O (4))lithium]

The crystal structure of the title compound, [Li(2)(C(4)H(2)N(3)O(4))(2)(H(2)O)(4)], contains centrosymmetric dinuclear mol­ecules in which two Li(I) ions are bridged by two water O atoms. The metal ion is coordinated by one N,O-bidentate ligand and three water O atoms (one of them is symmetry gener...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884415/
https://www.ncbi.nlm.nih.gov/pubmed/24427005
http://dx.doi.org/10.1107/S1600536813023167
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description The crystal structure of the title compound, [Li(2)(C(4)H(2)N(3)O(4))(2)(H(2)O)(4)], contains centrosymmetric dinuclear mol­ecules in which two Li(I) ions are bridged by two water O atoms. The metal ion is coordinated by one N,O-bidentate ligand and three water O atoms (one of them is symmetry generated), with one of the bridging water O atoms in the apical position of a distorted square pyramid. The carboxyl­ate group that participates in coordination to the metal ion remains protonated; the other is deprotonated and coordination inactive. An intra­molecular O—H⋯O hydrogen bond between carboxyl­ate groups is observed. In the crystal, dimers are linked by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-38844152014-01-14 Di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1H-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) N (3),O (4))lithium] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Li(2)(C(4)H(2)N(3)O(4))(2)(H(2)O)(4)], contains centrosymmetric dinuclear mol­ecules in which two Li(I) ions are bridged by two water O atoms. The metal ion is coordinated by one N,O-bidentate ligand and three water O atoms (one of them is symmetry generated), with one of the bridging water O atoms in the apical position of a distorted square pyramid. The carboxyl­ate group that participates in coordination to the metal ion remains protonated; the other is deprotonated and coordination inactive. An intra­molecular O—H⋯O hydrogen bond between carboxyl­ate groups is observed. In the crystal, dimers are linked by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884415/ /pubmed/24427005 http://dx.doi.org/10.1107/S1600536813023167 Text en © Starosta and Leciejewicz 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
Di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1H-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) N (3),O (4))lithium]
title Di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1H-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) N (3),O (4))lithium]
title_full Di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1H-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) N (3),O (4))lithium]
title_fullStr Di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1H-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) N (3),O (4))lithium]
title_full_unstemmed Di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1H-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) N (3),O (4))lithium]
title_short Di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1H-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) N (3),O (4))lithium]
title_sort di-μ-aqua-bis­[aqua­(5-carboxyl­ato-1h-1,2,3-triazole-4-carb­oxy­lic acid-κ(2) n (3),o (4))lithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884415/
https://www.ncbi.nlm.nih.gov/pubmed/24427005
http://dx.doi.org/10.1107/S1600536813023167
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