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Di-μ-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-κ(2) N (3),O (4))lithium]
The crystal structure of the title compound, [Li(2)(C(4)H(2)N(3)O(4))(2)(H(2)O)(4)], contains centrosymmetric dinuclear molecules in which two Li(I) ions are bridged by two water O atoms. The metal ion is coordinated by one N,O-bidentate ligand and three water O atoms (one of them is symmetry gener...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884415/ https://www.ncbi.nlm.nih.gov/pubmed/24427005 http://dx.doi.org/10.1107/S1600536813023167 |
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author | Starosta, Wojciech Leciejewicz, Janusz |
author_facet | Starosta, Wojciech Leciejewicz, Janusz |
author_sort | Starosta, Wojciech |
collection | PubMed |
description | The crystal structure of the title compound, [Li(2)(C(4)H(2)N(3)O(4))(2)(H(2)O)(4)], contains centrosymmetric dinuclear molecules in which two Li(I) ions are bridged by two water O atoms. The metal ion is coordinated by one N,O-bidentate ligand and three water O atoms (one of them is symmetry generated), with one of the bridging water O atoms in the apical position of a distorted square pyramid. The carboxylate group that participates in coordination to the metal ion remains protonated; the other is deprotonated and coordination inactive. An intramolecular O—H⋯O hydrogen bond between carboxylate groups is observed. In the crystal, dimers are linked by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, generating a three-dimensional network. |
format | Online Article Text |
id | pubmed-3884415 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844152014-01-14 Di-μ-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-κ(2) N (3),O (4))lithium] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Li(2)(C(4)H(2)N(3)O(4))(2)(H(2)O)(4)], contains centrosymmetric dinuclear molecules in which two Li(I) ions are bridged by two water O atoms. The metal ion is coordinated by one N,O-bidentate ligand and three water O atoms (one of them is symmetry generated), with one of the bridging water O atoms in the apical position of a distorted square pyramid. The carboxylate group that participates in coordination to the metal ion remains protonated; the other is deprotonated and coordination inactive. An intramolecular O—H⋯O hydrogen bond between carboxylate groups is observed. In the crystal, dimers are linked by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884415/ /pubmed/24427005 http://dx.doi.org/10.1107/S1600536813023167 Text en © Starosta and Leciejewicz 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Starosta, Wojciech Leciejewicz, Janusz Di-μ-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-κ(2) N (3),O (4))lithium] |
title | Di-μ-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-κ(2)
N
(3),O
(4))lithium] |
title_full | Di-μ-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-κ(2)
N
(3),O
(4))lithium] |
title_fullStr | Di-μ-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-κ(2)
N
(3),O
(4))lithium] |
title_full_unstemmed | Di-μ-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-κ(2)
N
(3),O
(4))lithium] |
title_short | Di-μ-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-κ(2)
N
(3),O
(4))lithium] |
title_sort | di-μ-aqua-bis[aqua(5-carboxylato-1h-1,2,3-triazole-4-carboxylic acid-κ(2)
n
(3),o
(4))lithium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884415/ https://www.ncbi.nlm.nih.gov/pubmed/24427005 http://dx.doi.org/10.1107/S1600536813023167 |
work_keys_str_mv | AT starostawojciech dimaquabisaqua5carboxylato1h123triazole4carboxylicacidk2n3o4lithium AT leciejewiczjanusz dimaquabisaqua5carboxylato1h123triazole4carboxylicacidk2n3o4lithium |