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2-(4-Bromobenzoyl)-1-ferrocenylspiro[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]
In the title compound, [Fe(C(5)H(5))(C(33)H(25)BrN(3)O)], the fused four-ring system, 11H-indeno[1,2-b]quinoxaline is essentially planar, with a maximum deviation of 0.087 (3) Å from the least-squares plane of the attached benzene ring. The pyrrolidine rings adopt envelope conformation and make a d...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884418/ https://www.ncbi.nlm.nih.gov/pubmed/24427003 http://dx.doi.org/10.1107/S1600536813023064 |
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author | Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan |
author_facet | Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan |
author_sort | Suhitha, Sivasubramanian |
collection | PubMed |
description | In the title compound, [Fe(C(5)H(5))(C(33)H(25)BrN(3)O)], the fused four-ring system, 11H-indeno[1,2-b]quinoxaline is essentially planar, with a maximum deviation of 0.087 (3) Å from the least-squares plane of the attached benzene ring. The pyrrolidine rings adopt envelope conformation and make a dihedral angle of 51.76 (19)° with each other. The cyclopentadiene rings of the ferrocenyl moiety have an eclipsed conformation. The Br atom deviates by 0.0190 (9) Å from the attached benzene ring. The molecular structure features an intramolecular C—H⋯N interaction, which generates an S(8) ring motif. The crystal packing features C—H⋯O interactions, which generate R (2) (2)(18) centrosymmetric dimers, as well as C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3884418 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844182014-01-14 2-(4-Bromobenzoyl)-1-ferrocenylspiro[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(33)H(25)BrN(3)O)], the fused four-ring system, 11H-indeno[1,2-b]quinoxaline is essentially planar, with a maximum deviation of 0.087 (3) Å from the least-squares plane of the attached benzene ring. The pyrrolidine rings adopt envelope conformation and make a dihedral angle of 51.76 (19)° with each other. The cyclopentadiene rings of the ferrocenyl moiety have an eclipsed conformation. The Br atom deviates by 0.0190 (9) Å from the attached benzene ring. The molecular structure features an intramolecular C—H⋯N interaction, which generates an S(8) ring motif. The crystal packing features C—H⋯O interactions, which generate R (2) (2)(18) centrosymmetric dimers, as well as C—H⋯π interactions. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884418/ /pubmed/24427003 http://dx.doi.org/10.1107/S1600536813023064 Text en © Suhitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan 2-(4-Bromobenzoyl)-1-ferrocenylspiro[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] |
title | 2-(4-Bromobenzoyl)-1-ferrocenylspiro[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] |
title_full | 2-(4-Bromobenzoyl)-1-ferrocenylspiro[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] |
title_fullStr | 2-(4-Bromobenzoyl)-1-ferrocenylspiro[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] |
title_full_unstemmed | 2-(4-Bromobenzoyl)-1-ferrocenylspiro[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] |
title_short | 2-(4-Bromobenzoyl)-1-ferrocenylspiro[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] |
title_sort | 2-(4-bromobenzoyl)-1-ferrocenylspiro[11h-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884418/ https://www.ncbi.nlm.nih.gov/pubmed/24427003 http://dx.doi.org/10.1107/S1600536813023064 |
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