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2-(4-Bromo­benzo­yl)-1-ferrocenyl­spiro­[11H-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline]

In the title compound, [Fe(C(5)H(5))(C(33)H(25)BrN(3)O)], the fused four-ring system, 11H-indeno­[1,2-b]quinoxaline is essentially planar, with a maximum deviation of 0.087 (3) Å from the least-squares plane of the attached benzene ring. The pyrrolidine rings adopt envelope conformation and make a d...

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Autores principales: Suhitha, Sivasubramanian, Gunasekaran, Krishnaswamy, Sureshbabu, Adukamparai Rajukrishnan, Raghunathan, Raghavachary, Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884418/
https://www.ncbi.nlm.nih.gov/pubmed/24427003
http://dx.doi.org/10.1107/S1600536813023064
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author Suhitha, Sivasubramanian
Gunasekaran, Krishnaswamy
Sureshbabu, Adukamparai Rajukrishnan
Raghunathan, Raghavachary
Velmurugan, Devadasan
author_facet Suhitha, Sivasubramanian
Gunasekaran, Krishnaswamy
Sureshbabu, Adukamparai Rajukrishnan
Raghunathan, Raghavachary
Velmurugan, Devadasan
author_sort Suhitha, Sivasubramanian
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(33)H(25)BrN(3)O)], the fused four-ring system, 11H-indeno­[1,2-b]quinoxaline is essentially planar, with a maximum deviation of 0.087 (3) Å from the least-squares plane of the attached benzene ring. The pyrrolidine rings adopt envelope conformation and make a dihedral angle of 51.76 (19)° with each other. The cyclopentadiene rings of the ferrocenyl moiety have an eclipsed conformation. The Br atom deviates by 0.0190 (9) Å from the attached benzene ring. The mol­ecular structure features an intra­molecular C—H⋯N inter­action, which generates an S(8) ring motif. The crystal packing features C—H⋯O inter­actions, which generate R (2) (2)(18) centrosymmetric dimers, as well as C—H⋯π inter­actions.
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spelling pubmed-38844182014-01-14 2-(4-Bromo­benzo­yl)-1-ferrocenyl­spiro­[11H-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline] Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(33)H(25)BrN(3)O)], the fused four-ring system, 11H-indeno­[1,2-b]quinoxaline is essentially planar, with a maximum deviation of 0.087 (3) Å from the least-squares plane of the attached benzene ring. The pyrrolidine rings adopt envelope conformation and make a dihedral angle of 51.76 (19)° with each other. The cyclopentadiene rings of the ferrocenyl moiety have an eclipsed conformation. The Br atom deviates by 0.0190 (9) Å from the attached benzene ring. The mol­ecular structure features an intra­molecular C—H⋯N inter­action, which generates an S(8) ring motif. The crystal packing features C—H⋯O inter­actions, which generate R (2) (2)(18) centrosymmetric dimers, as well as C—H⋯π inter­actions. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884418/ /pubmed/24427003 http://dx.doi.org/10.1107/S1600536813023064 Text en © Suhitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suhitha, Sivasubramanian
Gunasekaran, Krishnaswamy
Sureshbabu, Adukamparai Rajukrishnan
Raghunathan, Raghavachary
Velmurugan, Devadasan
2-(4-Bromo­benzo­yl)-1-ferrocenyl­spiro­[11H-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline]
title 2-(4-Bromo­benzo­yl)-1-ferrocenyl­spiro­[11H-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline]
title_full 2-(4-Bromo­benzo­yl)-1-ferrocenyl­spiro­[11H-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline]
title_fullStr 2-(4-Bromo­benzo­yl)-1-ferrocenyl­spiro­[11H-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline]
title_full_unstemmed 2-(4-Bromo­benzo­yl)-1-ferrocenyl­spiro­[11H-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline]
title_short 2-(4-Bromo­benzo­yl)-1-ferrocenyl­spiro­[11H-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline]
title_sort 2-(4-bromo­benzo­yl)-1-ferrocenyl­spiro­[11h-pyrrolidizine-3,11′-indeno­[1,2-b]quinoxaline]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884418/
https://www.ncbi.nlm.nih.gov/pubmed/24427003
http://dx.doi.org/10.1107/S1600536813023064
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