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3-Benzhydryl-1,3,4-thiadiazole-2(3H)-thione
In the title compound, C(15)H(12)N(2)S(2), the two phenyl rings and the planar (r.m.s. deviation = 0.002 Å) thiadiazole ring adopt a propeller conformation about the central C—H axis with H—C—C—C(phenyl) torsion angles of 44 and 42° and an H—C—N—C(thiadiazole) torsion angle of 28°. Intramolecula...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884419/ https://www.ncbi.nlm.nih.gov/pubmed/24427045 http://dx.doi.org/10.1107/S1600536813021867 |
Sumario: | In the title compound, C(15)H(12)N(2)S(2), the two phenyl rings and the planar (r.m.s. deviation = 0.002 Å) thiadiazole ring adopt a propeller conformation about the central C—H axis with H—C—C—C(phenyl) torsion angles of 44 and 42° and an H—C—N—C(thiadiazole) torsion angle of 28°. Intramolecular C—H⋯S and C—H⋯N contacts are observed. In the crystal, centrosymmetrically related molecules associate through C—H⋯π interactions. These are connected into a supramolecular chain along [101] by C—H⋯N interactions. |
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