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6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline]
In the title compound, [Fe(C(5)H(5))(C(32)H(24)N(3)OS)], both the thiazolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thiazolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the py...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884422/ https://www.ncbi.nlm.nih.gov/pubmed/24426995 http://dx.doi.org/10.1107/S1600536813022605 |
Sumario: | In the title compound, [Fe(C(5)H(5))(C(32)H(24)N(3)OS)], both the thiazolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thiazolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the pyrrolidine ring mean plane, which in turn makes a dihedral angle of 83.40 (10)° with the cyclopentane ring, indicating that the latter two rings are almost orthogonal to one another. In the crystal, a pair of C—H⋯O hydrogen bonds link the molecules forming inversion dimers. The dimers are linked via π–π interactions [centroid–centroid distance = 3.7764 (10) Å] involving the quinoxaline moieties forming chains propagating along [1-10]. |
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