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6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline]
In the title compound, [Fe(C(5)H(5))(C(32)H(24)N(3)OS)], both the thiazolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thiazolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the py...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884422/ https://www.ncbi.nlm.nih.gov/pubmed/24426995 http://dx.doi.org/10.1107/S1600536813022605 |
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author | Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan |
author_facet | Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan |
author_sort | Suhitha, Sivasubramanian |
collection | PubMed |
description | In the title compound, [Fe(C(5)H(5))(C(32)H(24)N(3)OS)], both the thiazolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thiazolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the pyrrolidine ring mean plane, which in turn makes a dihedral angle of 83.40 (10)° with the cyclopentane ring, indicating that the latter two rings are almost orthogonal to one another. In the crystal, a pair of C—H⋯O hydrogen bonds link the molecules forming inversion dimers. The dimers are linked via π–π interactions [centroid–centroid distance = 3.7764 (10) Å] involving the quinoxaline moieties forming chains propagating along [1-10]. |
format | Online Article Text |
id | pubmed-3884422 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844222014-01-14 6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(32)H(24)N(3)OS)], both the thiazolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thiazolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the pyrrolidine ring mean plane, which in turn makes a dihedral angle of 83.40 (10)° with the cyclopentane ring, indicating that the latter two rings are almost orthogonal to one another. In the crystal, a pair of C—H⋯O hydrogen bonds link the molecules forming inversion dimers. The dimers are linked via π–π interactions [centroid–centroid distance = 3.7764 (10) Å] involving the quinoxaline moieties forming chains propagating along [1-10]. International Union of Crystallography 2013-08-17 /pmc/articles/PMC3884422/ /pubmed/24426995 http://dx.doi.org/10.1107/S1600536813022605 Text en © Suhitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan 6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
title | 6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
title_full | 6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
title_fullStr | 6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
title_full_unstemmed | 6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
title_short | 6-Ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
title_sort | 6-ferrocenoyl-7-phenylspiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884422/ https://www.ncbi.nlm.nih.gov/pubmed/24426995 http://dx.doi.org/10.1107/S1600536813022605 |
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