Cargando…

6-Ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline]

In the title compound, [Fe(C(5)H(5))(C(32)H(24)N(3)OS)], both the thia­zolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thia­zolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the py...

Descripción completa

Detalles Bibliográficos
Autores principales: Suhitha, Sivasubramanian, Gunasekaran, Krishnaswamy, Sureshbabu, Adukamparai Rajukrishnan, Raghunathan, Raghavachary, Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884422/
https://www.ncbi.nlm.nih.gov/pubmed/24426995
http://dx.doi.org/10.1107/S1600536813022605
_version_ 1782298587034550272
author Suhitha, Sivasubramanian
Gunasekaran, Krishnaswamy
Sureshbabu, Adukamparai Rajukrishnan
Raghunathan, Raghavachary
Velmurugan, Devadasan
author_facet Suhitha, Sivasubramanian
Gunasekaran, Krishnaswamy
Sureshbabu, Adukamparai Rajukrishnan
Raghunathan, Raghavachary
Velmurugan, Devadasan
author_sort Suhitha, Sivasubramanian
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(32)H(24)N(3)OS)], both the thia­zolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thia­zolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the pyrrolidine ring mean plane, which in turn makes a dihedral angle of 83.40 (10)° with the cyclo­pentane ring, indicating that the latter two rings are almost orthogonal to one another. In the crystal, a pair of C—H⋯O hydrogen bonds link the mol­ecules forming inversion dimers. The dimers are linked via π–π inter­actions [centroid–centroid distance = 3.7764 (10) Å] involving the quinoxaline moieties forming chains propagating along [1-10].
format Online
Article
Text
id pubmed-3884422
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38844222014-01-14 6-Ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline] Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Sureshbabu, Adukamparai Rajukrishnan Raghunathan, Raghavachary Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(32)H(24)N(3)OS)], both the thia­zolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thia­zolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the pyrrolidine ring mean plane, which in turn makes a dihedral angle of 83.40 (10)° with the cyclo­pentane ring, indicating that the latter two rings are almost orthogonal to one another. In the crystal, a pair of C—H⋯O hydrogen bonds link the mol­ecules forming inversion dimers. The dimers are linked via π–π inter­actions [centroid–centroid distance = 3.7764 (10) Å] involving the quinoxaline moieties forming chains propagating along [1-10]. International Union of Crystallography 2013-08-17 /pmc/articles/PMC3884422/ /pubmed/24426995 http://dx.doi.org/10.1107/S1600536813022605 Text en © Suhitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suhitha, Sivasubramanian
Gunasekaran, Krishnaswamy
Sureshbabu, Adukamparai Rajukrishnan
Raghunathan, Raghavachary
Velmurugan, Devadasan
6-Ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline]
title 6-Ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline]
title_full 6-Ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline]
title_fullStr 6-Ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline]
title_full_unstemmed 6-Ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline]
title_short 6-Ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline]
title_sort 6-ferrocenoyl-7-phenyl­spiro­[hexa­hydro­pyrrolo­[1,2-c][1,3]thia­zole-5,11′-indeno­[1,2-b]quinoxaline]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884422/
https://www.ncbi.nlm.nih.gov/pubmed/24426995
http://dx.doi.org/10.1107/S1600536813022605
work_keys_str_mv AT suhithasivasubramanian 6ferrocenoyl7phenylspirohexahydropyrrolo12c13thiazole511indeno12bquinoxaline
AT gunasekarankrishnaswamy 6ferrocenoyl7phenylspirohexahydropyrrolo12c13thiazole511indeno12bquinoxaline
AT sureshbabuadukamparairajukrishnan 6ferrocenoyl7phenylspirohexahydropyrrolo12c13thiazole511indeno12bquinoxaline
AT raghunathanraghavachary 6ferrocenoyl7phenylspirohexahydropyrrolo12c13thiazole511indeno12bquinoxaline
AT velmurugandevadasan 6ferrocenoyl7phenylspirohexahydropyrrolo12c13thiazole511indeno12bquinoxaline