2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di­ethyl­dithio­carbamate

In the title compound, C(16)H(17)NO(3)S(2), the dihedral angles between the O/C/C/S group and the 2H-chromene ring system and the thio­carbamate group are 14.46 (9) and 83.30 (9)°, respectively. The bond-angle sum at the N atom is 360.0°. One of the methyl C atoms lies above the thio­carbamate plane...

Descripción completa

Detalles Bibliográficos
Autores principales: Meenakshi, T. G., Devarajegowda, H. C., Kumar, K. Mahesh, Kotresh, O., Devaru, Venkatesh B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884423/
https://www.ncbi.nlm.nih.gov/pubmed/24427080
http://dx.doi.org/10.1107/S1600536813021806
_version_ 1782298587261042688
author Meenakshi, T. G.
Devarajegowda, H. C.
Kumar, K. Mahesh
Kotresh, O.
Devaru, Venkatesh B.
author_facet Meenakshi, T. G.
Devarajegowda, H. C.
Kumar, K. Mahesh
Kotresh, O.
Devaru, Venkatesh B.
author_sort Meenakshi, T. G.
collection PubMed
description In the title compound, C(16)H(17)NO(3)S(2), the dihedral angles between the O/C/C/S group and the 2H-chromene ring system and the thio­carbamate group are 14.46 (9) and 83.30 (9)°, respectively. The bond-angle sum at the N atom is 360.0°. One of the methyl C atoms lies above the thio­carbamate plane and one lies below it [deviations = 1.264 (3) and −1.147 (3) Å, respectively]. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(10) loops. Weak aromatic π–π stacking inter­actions [shortest centroid–centroid distance = 3.8138 (11) Å] are also observed.
format Online
Article
Text
id pubmed-3884423
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38844232014-01-14 2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di­ethyl­dithio­carbamate Meenakshi, T. G. Devarajegowda, H. C. Kumar, K. Mahesh Kotresh, O. Devaru, Venkatesh B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(17)NO(3)S(2), the dihedral angles between the O/C/C/S group and the 2H-chromene ring system and the thio­carbamate group are 14.46 (9) and 83.30 (9)°, respectively. The bond-angle sum at the N atom is 360.0°. One of the methyl C atoms lies above the thio­carbamate plane and one lies below it [deviations = 1.264 (3) and −1.147 (3) Å, respectively]. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(10) loops. Weak aromatic π–π stacking inter­actions [shortest centroid–centroid distance = 3.8138 (11) Å] are also observed. International Union of Crystallography 2013-08-21 /pmc/articles/PMC3884423/ /pubmed/24427080 http://dx.doi.org/10.1107/S1600536813021806 Text en © Meenakshi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Meenakshi, T. G.
Devarajegowda, H. C.
Kumar, K. Mahesh
Kotresh, O.
Devaru, Venkatesh B.
2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di­ethyl­dithio­carbamate
title 2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di­ethyl­dithio­carbamate
title_full 2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di­ethyl­dithio­carbamate
title_fullStr 2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di­ethyl­dithio­carbamate
title_full_unstemmed 2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di­ethyl­dithio­carbamate
title_short 2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl di­ethyl­dithio­carbamate
title_sort 2-oxo-2-(2-oxo-2h-chromen-3-yl)ethyl di­ethyl­dithio­carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884423/
https://www.ncbi.nlm.nih.gov/pubmed/24427080
http://dx.doi.org/10.1107/S1600536813021806
work_keys_str_mv AT meenakshitg 2oxo22oxo2hchromen3ylethyldiethyldithiocarbamate
AT devarajegowdahc 2oxo22oxo2hchromen3ylethyldiethyldithiocarbamate
AT kumarkmahesh 2oxo22oxo2hchromen3ylethyldiethyldithiocarbamate
AT kotresho 2oxo22oxo2hchromen3ylethyldiethyldithiocarbamate
AT devaruvenkateshb 2oxo22oxo2hchromen3ylethyldiethyldithiocarbamate

Ejemplares similares