Cargando…
(4E)-4-[(2-Hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate
The asymmetric unit of the title compound, C(16)H(13)N(3)O(3)·0.5C(2)H(6)OS, is composed of two independent pyrazolidine-3,5-dione molecules and one dimethyl sulfoxide solvent molecule. In each pyrazolidine-3,5-dione molecule, an intramolecular N—H⋯O hydrogen bond forms an S(5)S(6) motif. In the...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884425/ https://www.ncbi.nlm.nih.gov/pubmed/24427046 http://dx.doi.org/10.1107/S1600536813022034 |
| _version_ | 1782298587708784640 |
|---|---|
| author | Akkurt, Mehmet Mohamed, Shaaban K. Elremaily, Mahmoud A. A. Ahmed, Eman. A. Albayati, Mustafa R. |
| author_facet | Akkurt, Mehmet Mohamed, Shaaban K. Elremaily, Mahmoud A. A. Ahmed, Eman. A. Albayati, Mustafa R. |
| author_sort | Akkurt, Mehmet |
| collection | PubMed |
| description | The asymmetric unit of the title compound, C(16)H(13)N(3)O(3)·0.5C(2)H(6)OS, is composed of two independent pyrazolidine-3,5-dione molecules and one dimethyl sulfoxide solvent molecule. In each pyrazolidine-3,5-dione molecule, an intramolecular N—H⋯O hydrogen bond forms an S(5)S(6) motif. In the crystal, pairs of each independent pyrazolidine-3,5-dione molecule are linked by N—H⋯O hydrogen bonds, forming dimers with R (2) (2)(8) motifs. These dimers are connected with the other molecules through the solvent molecules via O—H⋯O hydrogen bonds, forming ribbons along the b-axis direction. C—H⋯π interactions connect the ribbons. C—H⋯O interactions also occur. |
| format | Online Article Text |
| id | pubmed-3884425 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-38844252014-01-14 (4E)-4-[(2-Hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate Akkurt, Mehmet Mohamed, Shaaban K. Elremaily, Mahmoud A. A. Ahmed, Eman. A. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(16)H(13)N(3)O(3)·0.5C(2)H(6)OS, is composed of two independent pyrazolidine-3,5-dione molecules and one dimethyl sulfoxide solvent molecule. In each pyrazolidine-3,5-dione molecule, an intramolecular N—H⋯O hydrogen bond forms an S(5)S(6) motif. In the crystal, pairs of each independent pyrazolidine-3,5-dione molecule are linked by N—H⋯O hydrogen bonds, forming dimers with R (2) (2)(8) motifs. These dimers are connected with the other molecules through the solvent molecules via O—H⋯O hydrogen bonds, forming ribbons along the b-axis direction. C—H⋯π interactions connect the ribbons. C—H⋯O interactions also occur. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884425/ /pubmed/24427046 http://dx.doi.org/10.1107/S1600536813022034 Text en © Akkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Akkurt, Mehmet Mohamed, Shaaban K. Elremaily, Mahmoud A. A. Ahmed, Eman. A. Albayati, Mustafa R. (4E)-4-[(2-Hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate |
| title | (4E)-4-[(2-Hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate |
| title_full | (4E)-4-[(2-Hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate |
| title_fullStr | (4E)-4-[(2-Hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate |
| title_full_unstemmed | (4E)-4-[(2-Hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate |
| title_short | (4E)-4-[(2-Hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate |
| title_sort | (4e)-4-[(2-hydroxyanilino)methylidene]-1-phenylpyrazolidine-3,5-dione dimethyl sulfoxide hemisolvate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884425/ https://www.ncbi.nlm.nih.gov/pubmed/24427046 http://dx.doi.org/10.1107/S1600536813022034 |
| work_keys_str_mv | AT akkurtmehmet 4e42hydroxyanilinomethylidene1phenylpyrazolidine35dionedimethylsulfoxidehemisolvate AT mohamedshaabank 4e42hydroxyanilinomethylidene1phenylpyrazolidine35dionedimethylsulfoxidehemisolvate AT elremailymahmoudaa 4e42hydroxyanilinomethylidene1phenylpyrazolidine35dionedimethylsulfoxidehemisolvate AT ahmedemana 4e42hydroxyanilinomethylidene1phenylpyrazolidine35dionedimethylsulfoxidehemisolvate AT albayatimustafar 4e42hydroxyanilinomethylidene1phenylpyrazolidine35dionedimethylsulfoxidehemisolvate |