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5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan

The asymmetric unit of the title compound, C(26)H(23)FO(2)S, contains two independent mol­ecules (A and B), in both of which the cyclo­hexyl ring adopts a chair conformation. The benzo­furan ring systems, the 4-fluoro­phenyl and phenyl rings are essentially planar, with r.m.s. deviations of 0.008 (1...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884427/
https://www.ncbi.nlm.nih.gov/pubmed/24427078
http://dx.doi.org/10.1107/S1600536813022678
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author Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description The asymmetric unit of the title compound, C(26)H(23)FO(2)S, contains two independent mol­ecules (A and B), in both of which the cyclo­hexyl ring adopts a chair conformation. The benzo­furan ring systems, the 4-fluoro­phenyl and phenyl rings are essentially planar, with r.m.s. deviations of 0.008 (1), 0.002 (1) and 0.003 (1) Å, respectively, for mol­ecule A, and 0.016 (1), 0.004 (1) and 0.002 (1) Å, respectively, for mol­ecule B. The dihedral angles between the benzo­furan ring system and the pendant 4-fluoro­phenyl and phenyl rings are 12.3 (7) and 85.42 (4)°, respectively, for mol­ecule A, and 39.67 (6) and 72.17 (4)°, respectively, for mol­ecule B. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π inter­actions, resulting in a three-dimensional network.
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spelling pubmed-38844272014-01-14 5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan Choi, Hong Dae Seo, Pil Ja Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(26)H(23)FO(2)S, contains two independent mol­ecules (A and B), in both of which the cyclo­hexyl ring adopts a chair conformation. The benzo­furan ring systems, the 4-fluoro­phenyl and phenyl rings are essentially planar, with r.m.s. deviations of 0.008 (1), 0.002 (1) and 0.003 (1) Å, respectively, for mol­ecule A, and 0.016 (1), 0.004 (1) and 0.002 (1) Å, respectively, for mol­ecule B. The dihedral angles between the benzo­furan ring system and the pendant 4-fluoro­phenyl and phenyl rings are 12.3 (7) and 85.42 (4)°, respectively, for mol­ecule A, and 39.67 (6) and 72.17 (4)°, respectively, for mol­ecule B. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π inter­actions, resulting in a three-dimensional network. International Union of Crystallography 2013-08-21 /pmc/articles/PMC3884427/ /pubmed/24427078 http://dx.doi.org/10.1107/S1600536813022678 Text en © Choi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan
title 5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan
title_full 5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan
title_fullStr 5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan
title_full_unstemmed 5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan
title_short 5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan
title_sort 5-cyclo­hexyl-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884427/
https://www.ncbi.nlm.nih.gov/pubmed/24427078
http://dx.doi.org/10.1107/S1600536813022678
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