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Tetrakis(μ-2-phenylacetato-κ(2) O:O′)bis{[4-(dimethylamino)pyridine-κN (1)]cobalt(II)}
The title compound, [Co(2)(C(8)H(7)O(2))(4)(C(7)H(10)N(2))(2)], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenylacetate ligands in syn–syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxylate ligand...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884428/ https://www.ncbi.nlm.nih.gov/pubmed/24427006 http://dx.doi.org/10.1107/S1600536813023258 |
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author | Benslimane, Meriem Redjel, Yasmine Kheira Dénès, Georges Merazig, Hocine |
author_facet | Benslimane, Meriem Redjel, Yasmine Kheira Dénès, Georges Merazig, Hocine |
author_sort | Benslimane, Meriem |
collection | PubMed |
description | The title compound, [Co(2)(C(8)H(7)O(2))(4)(C(7)H(10)N(2))(2)], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenylacetate ligands in syn–syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O interactions link the dinuclear complex molecules into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3884428 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844282014-01-14 Tetrakis(μ-2-phenylacetato-κ(2) O:O′)bis{[4-(dimethylamino)pyridine-κN (1)]cobalt(II)} Benslimane, Meriem Redjel, Yasmine Kheira Dénès, Georges Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(2)(C(8)H(7)O(2))(4)(C(7)H(10)N(2))(2)], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenylacetate ligands in syn–syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino)pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O interactions link the dinuclear complex molecules into a three-dimensional network. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884428/ /pubmed/24427006 http://dx.doi.org/10.1107/S1600536813023258 Text en © Benslimane et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Benslimane, Meriem Redjel, Yasmine Kheira Dénès, Georges Merazig, Hocine Tetrakis(μ-2-phenylacetato-κ(2) O:O′)bis{[4-(dimethylamino)pyridine-κN (1)]cobalt(II)} |
title | Tetrakis(μ-2-phenylacetato-κ(2)
O:O′)bis{[4-(dimethylamino)pyridine-κN
(1)]cobalt(II)} |
title_full | Tetrakis(μ-2-phenylacetato-κ(2)
O:O′)bis{[4-(dimethylamino)pyridine-κN
(1)]cobalt(II)} |
title_fullStr | Tetrakis(μ-2-phenylacetato-κ(2)
O:O′)bis{[4-(dimethylamino)pyridine-κN
(1)]cobalt(II)} |
title_full_unstemmed | Tetrakis(μ-2-phenylacetato-κ(2)
O:O′)bis{[4-(dimethylamino)pyridine-κN
(1)]cobalt(II)} |
title_short | Tetrakis(μ-2-phenylacetato-κ(2)
O:O′)bis{[4-(dimethylamino)pyridine-κN
(1)]cobalt(II)} |
title_sort | tetrakis(μ-2-phenylacetato-κ(2)
o:o′)bis{[4-(dimethylamino)pyridine-κn
(1)]cobalt(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884428/ https://www.ncbi.nlm.nih.gov/pubmed/24427006 http://dx.doi.org/10.1107/S1600536813023258 |
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