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Tetra­kis(μ-2-phenyl­acetato-κ(2) O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN (1)]cobalt(II)}

The title compound, [Co(2)(C(8)H(7)O(2))(4)(C(7)H(10)N(2))(2)], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenyl­acetate ligands in syn–syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxyl­ate ligand...

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Autores principales: Benslimane, Meriem, Redjel, Yasmine Kheira, Dénès, Georges, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884428/
https://www.ncbi.nlm.nih.gov/pubmed/24427006
http://dx.doi.org/10.1107/S1600536813023258
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author Benslimane, Meriem
Redjel, Yasmine Kheira
Dénès, Georges
Merazig, Hocine
author_facet Benslimane, Meriem
Redjel, Yasmine Kheira
Dénès, Georges
Merazig, Hocine
author_sort Benslimane, Meriem
collection PubMed
description The title compound, [Co(2)(C(8)H(7)O(2))(4)(C(7)H(10)N(2))(2)], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenyl­acetate ligands in syn–syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxyl­ate ligands and the ring N atom of a 4-(di­methyl­amino)­pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O inter­actions link the dinuclear complex mol­ecules into a three-dimensional network.
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spelling pubmed-38844282014-01-14 Tetra­kis(μ-2-phenyl­acetato-κ(2) O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN (1)]cobalt(II)} Benslimane, Meriem Redjel, Yasmine Kheira Dénès, Georges Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(2)(C(8)H(7)O(2))(4)(C(7)H(10)N(2))(2)], crystallizes as a centrosymmetric dimer containing two Co(II) atoms bridged by four bidentate phenyl­acetate ligands in syn–syn bridging modes. Each Co(II) atom is five-coordinated by four O atoms from four different carboxyl­ate ligands and the ring N atom of a 4-(di­methyl­amino)­pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C—H⋯O inter­actions link the dinuclear complex mol­ecules into a three-dimensional network. International Union of Crystallography 2013-08-23 /pmc/articles/PMC3884428/ /pubmed/24427006 http://dx.doi.org/10.1107/S1600536813023258 Text en © Benslimane et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Benslimane, Meriem
Redjel, Yasmine Kheira
Dénès, Georges
Merazig, Hocine
Tetra­kis(μ-2-phenyl­acetato-κ(2) O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN (1)]cobalt(II)}
title Tetra­kis(μ-2-phenyl­acetato-κ(2) O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN (1)]cobalt(II)}
title_full Tetra­kis(μ-2-phenyl­acetato-κ(2) O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN (1)]cobalt(II)}
title_fullStr Tetra­kis(μ-2-phenyl­acetato-κ(2) O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN (1)]cobalt(II)}
title_full_unstemmed Tetra­kis(μ-2-phenyl­acetato-κ(2) O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN (1)]cobalt(II)}
title_short Tetra­kis(μ-2-phenyl­acetato-κ(2) O:O′)bis­{[4-(di­methyl­amino)­pyridine-κN (1)]cobalt(II)}
title_sort tetra­kis(μ-2-phenyl­acetato-κ(2) o:o′)bis­{[4-(di­methyl­amino)­pyridine-κn (1)]cobalt(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884428/
https://www.ncbi.nlm.nih.gov/pubmed/24427006
http://dx.doi.org/10.1107/S1600536813023258
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