tert-Butyl N-(thio­phen-2-yl)carbamate

In the title compound, C(9)H(13)NO(2)S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intra­molecular C—H⋯O inter­actions in tandem with the tert-butyl groups render the packing of adjacent mol­ecules in the [001] direction nearly per...

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Detalles Bibliográficos
Autores principales: Hsu, Gene C., Singer, Laci M., Cordes, David B., Findlater, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884429/
https://www.ncbi.nlm.nih.gov/pubmed/24427049
http://dx.doi.org/10.1107/S160053681302196X
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author Hsu, Gene C.
Singer, Laci M.
Cordes, David B.
Findlater, Michael
author_facet Hsu, Gene C.
Singer, Laci M.
Cordes, David B.
Findlater, Michael
author_sort Hsu, Gene C.
collection PubMed
description In the title compound, C(9)H(13)NO(2)S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intra­molecular C—H⋯O inter­actions in tandem with the tert-butyl groups render the packing of adjacent mol­ecules in the [001] direction nearly perpendicular [the angle between adjacent thio­phene rings is 74.83 (7)°]. An inter­molecular N—H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.
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spelling pubmed-38844292014-01-14 tert-Butyl N-(thio­phen-2-yl)carbamate Hsu, Gene C. Singer, Laci M. Cordes, David B. Findlater, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(13)NO(2)S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intra­molecular C—H⋯O inter­actions in tandem with the tert-butyl groups render the packing of adjacent mol­ecules in the [001] direction nearly perpendicular [the angle between adjacent thio­phene rings is 74.83 (7)°]. An inter­molecular N—H⋯O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin. International Union of Crystallography 2013-08-14 /pmc/articles/PMC3884429/ /pubmed/24427049 http://dx.doi.org/10.1107/S160053681302196X Text en © Hsu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hsu, Gene C.
Singer, Laci M.
Cordes, David B.
Findlater, Michael
tert-Butyl N-(thio­phen-2-yl)carbamate
title tert-Butyl N-(thio­phen-2-yl)carbamate
title_full tert-Butyl N-(thio­phen-2-yl)carbamate
title_fullStr tert-Butyl N-(thio­phen-2-yl)carbamate
title_full_unstemmed tert-Butyl N-(thio­phen-2-yl)carbamate
title_short tert-Butyl N-(thio­phen-2-yl)carbamate
title_sort tert-butyl n-(thio­phen-2-yl)carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884429/
https://www.ncbi.nlm.nih.gov/pubmed/24427049
http://dx.doi.org/10.1107/S160053681302196X
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