Cargando…

Di­aqua­dichlorido­bis­(pyridine-κN)cobalt(II)

The title mol­ecule, [CoCl(2)(C(5)H(5)N)(2)(H(2)O)(2)], has -1 symmetry with the Co(II) ion situated on an inversion centre. The cation has a distorted octa­hedral coordination environment and is surrounded by two N and two Cl atoms in the equatorial plane, while the coordinating water O atoms occup...

Descripción completa

Detalles Bibliográficos
Autores principales: Kannan, P.S., Ganeshraja, A. S., Anbalagan, K., Govindan, E., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884431/
https://www.ncbi.nlm.nih.gov/pubmed/24427001
http://dx.doi.org/10.1107/S1600536813022484
_version_ 1782298589368680448
author Kannan, P.S.
Ganeshraja, A. S.
Anbalagan, K.
Govindan, E.
SubbiahPandi, A.
author_facet Kannan, P.S.
Ganeshraja, A. S.
Anbalagan, K.
Govindan, E.
SubbiahPandi, A.
author_sort Kannan, P.S.
collection PubMed
description The title mol­ecule, [CoCl(2)(C(5)H(5)N)(2)(H(2)O)(2)], has -1 symmetry with the Co(II) ion situated on an inversion centre. The cation has a distorted octa­hedral coordination environment and is surrounded by two N and two Cl atoms in the equatorial plane, while the coordinating water O atoms occupy the axial positions. The crystal exhibits nonmerohedral twinning with two domain states, the volume fractions of which were refined to 0.883 (2) and 0.117 (3). The crystal packing is stabilized by O—H⋯Cl hydrogen-bond inter­actions, forming two-dimensional networks lying parallel to (001). The crystal packing also features π–π inter­actions between the pyridine rings, with centroid–centroid separations of 3.493 (3) and 3.545 (3) Å.
format Online
Article
Text
id pubmed-3884431
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38844312014-01-14 Di­aqua­dichlorido­bis­(pyridine-κN)cobalt(II) Kannan, P.S. Ganeshraja, A. S. Anbalagan, K. Govindan, E. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mol­ecule, [CoCl(2)(C(5)H(5)N)(2)(H(2)O)(2)], has -1 symmetry with the Co(II) ion situated on an inversion centre. The cation has a distorted octa­hedral coordination environment and is surrounded by two N and two Cl atoms in the equatorial plane, while the coordinating water O atoms occupy the axial positions. The crystal exhibits nonmerohedral twinning with two domain states, the volume fractions of which were refined to 0.883 (2) and 0.117 (3). The crystal packing is stabilized by O—H⋯Cl hydrogen-bond inter­actions, forming two-dimensional networks lying parallel to (001). The crystal packing also features π–π inter­actions between the pyridine rings, with centroid–centroid separations of 3.493 (3) and 3.545 (3) Å. International Union of Crystallography 2013-08-21 /pmc/articles/PMC3884431/ /pubmed/24427001 http://dx.doi.org/10.1107/S1600536813022484 Text en © Kannan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kannan, P.S.
Ganeshraja, A. S.
Anbalagan, K.
Govindan, E.
SubbiahPandi, A.
Di­aqua­dichlorido­bis­(pyridine-κN)cobalt(II)
title Di­aqua­dichlorido­bis­(pyridine-κN)cobalt(II)
title_full Di­aqua­dichlorido­bis­(pyridine-κN)cobalt(II)
title_fullStr Di­aqua­dichlorido­bis­(pyridine-κN)cobalt(II)
title_full_unstemmed Di­aqua­dichlorido­bis­(pyridine-κN)cobalt(II)
title_short Di­aqua­dichlorido­bis­(pyridine-κN)cobalt(II)
title_sort di­aqua­dichlorido­bis­(pyridine-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884431/
https://www.ncbi.nlm.nih.gov/pubmed/24427001
http://dx.doi.org/10.1107/S1600536813022484
work_keys_str_mv AT kannanps diaquadichloridobispyridinekncobaltii
AT ganeshrajaas diaquadichloridobispyridinekncobaltii
AT anbalagank diaquadichloridobispyridinekncobaltii
AT govindane diaquadichloridobispyridinekncobaltii
AT subbiahpandia diaquadichloridobispyridinekncobaltii