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Epibisdehydroneotuberostemonine J
The title compound, C(22)H(29)NO(4), a stemona alkaloid, is composed of two lactone rings (A and E), a six-membered ring (B), a pyrrole ring (C) and a seven-membered ring (D). The five-membered rings A and E exhibit envelope conformations (C atoms as flaps) while ring C is planar. Ring B exhibits a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884435/ https://www.ncbi.nlm.nih.gov/pubmed/24427015 http://dx.doi.org/10.1107/S1600536813021077 |
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author | Jin, Lu Zhang, Rong-Rong Tian, Hai-Yan But, Paul Pui-Hay Jiang, Ren-Wang |
author_facet | Jin, Lu Zhang, Rong-Rong Tian, Hai-Yan But, Paul Pui-Hay Jiang, Ren-Wang |
author_sort | Jin, Lu |
collection | PubMed |
description | The title compound, C(22)H(29)NO(4), a stemona alkaloid, is composed of two lactone rings (A and E), a six-membered ring (B), a pyrrole ring (C) and a seven-membered ring (D). The five-membered rings A and E exhibit envelope conformations (C atoms as flaps) while ring C is planar. Ring B exhibits a twist-chair conformation due to fusion with pyrrole ring C while ring D adopts a chair conformation. The junction between rings A and B is cis. In the crystal, weak C—H⋯O interactions involving the two carbonyl groups, a methylene and a methyl group give rise to a three-dimensional network. |
format | Online Article Text |
id | pubmed-3884435 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844352014-01-14 Epibisdehydroneotuberostemonine J Jin, Lu Zhang, Rong-Rong Tian, Hai-Yan But, Paul Pui-Hay Jiang, Ren-Wang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(29)NO(4), a stemona alkaloid, is composed of two lactone rings (A and E), a six-membered ring (B), a pyrrole ring (C) and a seven-membered ring (D). The five-membered rings A and E exhibit envelope conformations (C atoms as flaps) while ring C is planar. Ring B exhibits a twist-chair conformation due to fusion with pyrrole ring C while ring D adopts a chair conformation. The junction between rings A and B is cis. In the crystal, weak C—H⋯O interactions involving the two carbonyl groups, a methylene and a methyl group give rise to a three-dimensional network. International Union of Crystallography 2013-08-03 /pmc/articles/PMC3884435/ /pubmed/24427015 http://dx.doi.org/10.1107/S1600536813021077 Text en © Jin et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jin, Lu Zhang, Rong-Rong Tian, Hai-Yan But, Paul Pui-Hay Jiang, Ren-Wang Epibisdehydroneotuberostemonine J |
title | Epibisdehydroneotuberostemonine J |
title_full | Epibisdehydroneotuberostemonine J |
title_fullStr | Epibisdehydroneotuberostemonine J |
title_full_unstemmed | Epibisdehydroneotuberostemonine J |
title_short | Epibisdehydroneotuberostemonine J |
title_sort | epibisdehydroneotuberostemonine j |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884435/ https://www.ncbi.nlm.nih.gov/pubmed/24427015 http://dx.doi.org/10.1107/S1600536813021077 |
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