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Epibisde­hydro­neotuberostemonine J

The title compound, C(22)H(29)NO(4), a stemona alkaloid, is composed of two lactone rings (A and E), a six-membered ring (B), a pyrrole ring (C) and a seven-membered ring (D). The five-membered rings A and E exhibit envelope conformations (C atoms as flaps) while ring C is planar. Ring B exhibits a...

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Autores principales: Jin, Lu, Zhang, Rong-Rong, Tian, Hai-Yan, But, Paul Pui-Hay, Jiang, Ren-Wang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884435/
https://www.ncbi.nlm.nih.gov/pubmed/24427015
http://dx.doi.org/10.1107/S1600536813021077
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author Jin, Lu
Zhang, Rong-Rong
Tian, Hai-Yan
But, Paul Pui-Hay
Jiang, Ren-Wang
author_facet Jin, Lu
Zhang, Rong-Rong
Tian, Hai-Yan
But, Paul Pui-Hay
Jiang, Ren-Wang
author_sort Jin, Lu
collection PubMed
description The title compound, C(22)H(29)NO(4), a stemona alkaloid, is composed of two lactone rings (A and E), a six-membered ring (B), a pyrrole ring (C) and a seven-membered ring (D). The five-membered rings A and E exhibit envelope conformations (C atoms as flaps) while ring C is planar. Ring B exhibits a twist-chair conformation due to fusion with pyrrole ring C while ring D adopts a chair conformation. The junction between rings A and B is cis. In the crystal, weak C—H⋯O inter­actions involving the two carbonyl groups, a methyl­ene and a methyl group give rise to a three-dimensional network.
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spelling pubmed-38844352014-01-14 Epibisde­hydro­neotuberostemonine J Jin, Lu Zhang, Rong-Rong Tian, Hai-Yan But, Paul Pui-Hay Jiang, Ren-Wang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(29)NO(4), a stemona alkaloid, is composed of two lactone rings (A and E), a six-membered ring (B), a pyrrole ring (C) and a seven-membered ring (D). The five-membered rings A and E exhibit envelope conformations (C atoms as flaps) while ring C is planar. Ring B exhibits a twist-chair conformation due to fusion with pyrrole ring C while ring D adopts a chair conformation. The junction between rings A and B is cis. In the crystal, weak C—H⋯O inter­actions involving the two carbonyl groups, a methyl­ene and a methyl group give rise to a three-dimensional network. International Union of Crystallography 2013-08-03 /pmc/articles/PMC3884435/ /pubmed/24427015 http://dx.doi.org/10.1107/S1600536813021077 Text en © Jin et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jin, Lu
Zhang, Rong-Rong
Tian, Hai-Yan
But, Paul Pui-Hay
Jiang, Ren-Wang
Epibisde­hydro­neotuberostemonine J
title Epibisde­hydro­neotuberostemonine J
title_full Epibisde­hydro­neotuberostemonine J
title_fullStr Epibisde­hydro­neotuberostemonine J
title_full_unstemmed Epibisde­hydro­neotuberostemonine J
title_short Epibisde­hydro­neotuberostemonine J
title_sort epibisde­hydro­neotuberostemonine j
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884435/
https://www.ncbi.nlm.nih.gov/pubmed/24427015
http://dx.doi.org/10.1107/S1600536813021077
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