N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide

The asymmetric unit of the title compound, C(22)H(18)N(4)O(2)S(2), contains two mol­ecules. In one of them, the dihedral angles between the central benzene ring and the phenyl rings are 16.97 (8) and 20.97 (8)°, while the phenyl rings make a dihedral angle of 37.87 (8)°. In the other mol­ecule, the...

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Detalles Bibliográficos
Autores principales: Ngaini, Zainab, Mohd Ariff, Maya Asyikin, Wan Zullkiplee, Wan Sharifatun Handayani, Hussain, Hasnain, Rosli, Mohd Mustaqim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884437/
https://www.ncbi.nlm.nih.gov/pubmed/24427019
http://dx.doi.org/10.1107/S1600536813020163
Descripción
Sumario:The asymmetric unit of the title compound, C(22)H(18)N(4)O(2)S(2), contains two mol­ecules. In one of them, the dihedral angles between the central benzene ring and the phenyl rings are 16.97 (8) and 20.97 (8)°, while the phenyl rings make a dihedral angle of 37.87 (8)°. In the other mol­ecule, the corresponding values are 34.92 (7), 53.90 (7) and 60.68 (8)°, respectively. In each mol­ecule, two intra­molecular N—H⋯O hydrogen bonds generate S(6) rings and a short C—H⋯S contact also occurs. In the crystal, N—H⋯S, N—H⋯O, C—H⋯O and C—H⋯S inter­actions link the mol­ecules into a three-dimensional network.

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