N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide

The asymmetric unit of the title compound, C(22)H(18)N(4)O(2)S(2), contains two mol­ecules. In one of them, the dihedral angles between the central benzene ring and the phenyl rings are 16.97 (8) and 20.97 (8)°, while the phenyl rings make a dihedral angle of 37.87 (8)°. In the other mol­ecule, the...

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Autores principales: Ngaini, Zainab, Mohd Ariff, Maya Asyikin, Wan Zullkiplee, Wan Sharifatun Handayani, Hussain, Hasnain, Rosli, Mohd Mustaqim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884437/
https://www.ncbi.nlm.nih.gov/pubmed/24427019
http://dx.doi.org/10.1107/S1600536813020163
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author Ngaini, Zainab
Mohd Ariff, Maya Asyikin
Wan Zullkiplee, Wan Sharifatun Handayani
Hussain, Hasnain
Rosli, Mohd Mustaqim
author_facet Ngaini, Zainab
Mohd Ariff, Maya Asyikin
Wan Zullkiplee, Wan Sharifatun Handayani
Hussain, Hasnain
Rosli, Mohd Mustaqim
author_sort Ngaini, Zainab
collection PubMed
description The asymmetric unit of the title compound, C(22)H(18)N(4)O(2)S(2), contains two mol­ecules. In one of them, the dihedral angles between the central benzene ring and the phenyl rings are 16.97 (8) and 20.97 (8)°, while the phenyl rings make a dihedral angle of 37.87 (8)°. In the other mol­ecule, the corresponding values are 34.92 (7), 53.90 (7) and 60.68 (8)°, respectively. In each mol­ecule, two intra­molecular N—H⋯O hydrogen bonds generate S(6) rings and a short C—H⋯S contact also occurs. In the crystal, N—H⋯S, N—H⋯O, C—H⋯O and C—H⋯S inter­actions link the mol­ecules into a three-dimensional network.
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spelling pubmed-38844372014-01-14 N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide Ngaini, Zainab Mohd Ariff, Maya Asyikin Wan Zullkiplee, Wan Sharifatun Handayani Hussain, Hasnain Rosli, Mohd Mustaqim Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(18)N(4)O(2)S(2), contains two mol­ecules. In one of them, the dihedral angles between the central benzene ring and the phenyl rings are 16.97 (8) and 20.97 (8)°, while the phenyl rings make a dihedral angle of 37.87 (8)°. In the other mol­ecule, the corresponding values are 34.92 (7), 53.90 (7) and 60.68 (8)°, respectively. In each mol­ecule, two intra­molecular N—H⋯O hydrogen bonds generate S(6) rings and a short C—H⋯S contact also occurs. In the crystal, N—H⋯S, N—H⋯O, C—H⋯O and C—H⋯S inter­actions link the mol­ecules into a three-dimensional network. International Union of Crystallography 2013-08-03 /pmc/articles/PMC3884437/ /pubmed/24427019 http://dx.doi.org/10.1107/S1600536813020163 Text en © Ngaini et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ngaini, Zainab
Mohd Ariff, Maya Asyikin
Wan Zullkiplee, Wan Sharifatun Handayani
Hussain, Hasnain
Rosli, Mohd Mustaqim
N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide
title N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide
title_full N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide
title_fullStr N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide
title_full_unstemmed N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide
title_short N,N′-Bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide
title_sort n,n′-bis(phenyl­carbamo­thio­yl)benzene-1,3-dicarboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884437/
https://www.ncbi.nlm.nih.gov/pubmed/24427019
http://dx.doi.org/10.1107/S1600536813020163
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