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Dipotassium tetraaquabis(μ-citrato-κ(4) O:O′,O′′,O′′′)nickelate(II) tetrahydrate
The title complex, K(2)[Ni(2)(C(6)H(5)O(7))(2)(H(2)O)(4)]·4H(2)O, is a dinuclear centrosymmetric anionic octahedral complex, involving citrates as tridentate and bridging ligands, and coordinating water molecules. An extensive network of hydrogen bonds connects the complex anions through the two...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884440/ https://www.ncbi.nlm.nih.gov/pubmed/24426997 http://dx.doi.org/10.1107/S1600536813022630 |
| _version_ | 1782298591396626432 |
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| author | Yao, Hua-Gang Huang, Jia-Na Deng, Run-Kang Yao, Zhi-Bang |
| author_facet | Yao, Hua-Gang Huang, Jia-Na Deng, Run-Kang Yao, Zhi-Bang |
| author_sort | Yao, Hua-Gang |
| collection | PubMed |
| description | The title complex, K(2)[Ni(2)(C(6)H(5)O(7))(2)(H(2)O)(4)]·4H(2)O, is a dinuclear centrosymmetric anionic octahedral complex, involving citrates as tridentate and bridging ligands, and coordinating water molecules. An extensive network of hydrogen bonds connects the complex anions through the two unique uncoordinating water molecules. The K(+) counter cation is surrounded by seven O atoms in the form of an irregular polyhedron and further stabilizes the crystal packing. |
| format | Online Article Text |
| id | pubmed-3884440 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-38844402014-01-14 Dipotassium tetraaquabis(μ-citrato-κ(4) O:O′,O′′,O′′′)nickelate(II) tetrahydrate Yao, Hua-Gang Huang, Jia-Na Deng, Run-Kang Yao, Zhi-Bang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, K(2)[Ni(2)(C(6)H(5)O(7))(2)(H(2)O)(4)]·4H(2)O, is a dinuclear centrosymmetric anionic octahedral complex, involving citrates as tridentate and bridging ligands, and coordinating water molecules. An extensive network of hydrogen bonds connects the complex anions through the two unique uncoordinating water molecules. The K(+) counter cation is surrounded by seven O atoms in the form of an irregular polyhedron and further stabilizes the crystal packing. International Union of Crystallography 2013-08-17 /pmc/articles/PMC3884440/ /pubmed/24426997 http://dx.doi.org/10.1107/S1600536813022630 Text en © Yao et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yao, Hua-Gang Huang, Jia-Na Deng, Run-Kang Yao, Zhi-Bang Dipotassium tetraaquabis(μ-citrato-κ(4) O:O′,O′′,O′′′)nickelate(II) tetrahydrate |
| title | Dipotassium tetraaquabis(μ-citrato-κ(4)
O:O′,O′′,O′′′)nickelate(II) tetrahydrate |
| title_full | Dipotassium tetraaquabis(μ-citrato-κ(4)
O:O′,O′′,O′′′)nickelate(II) tetrahydrate |
| title_fullStr | Dipotassium tetraaquabis(μ-citrato-κ(4)
O:O′,O′′,O′′′)nickelate(II) tetrahydrate |
| title_full_unstemmed | Dipotassium tetraaquabis(μ-citrato-κ(4)
O:O′,O′′,O′′′)nickelate(II) tetrahydrate |
| title_short | Dipotassium tetraaquabis(μ-citrato-κ(4)
O:O′,O′′,O′′′)nickelate(II) tetrahydrate |
| title_sort | dipotassium tetraaquabis(μ-citrato-κ(4)
o:o′,o′′,o′′′)nickelate(ii) tetrahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884440/ https://www.ncbi.nlm.nih.gov/pubmed/24426997 http://dx.doi.org/10.1107/S1600536813022630 |
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