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catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))]

In the title compound, [Fe(NCS)(2)(C(8)H(6)N(4)S(2))(2)](n), the Fe(II) cation is coordinated by two terminal N-bonded thio­cyanate anions and four bridging N:N′-bridging dipyrazin-2-yl di­sulfide ligands in an octa­hedral geometry. The Fe(II) cations are connected via bridging 4,4′-di­pyrazine liga...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884442/
https://www.ncbi.nlm.nih.gov/pubmed/24426987
http://dx.doi.org/10.1107/S1600536813021958
Descripción
Sumario:In the title compound, [Fe(NCS)(2)(C(8)H(6)N(4)S(2))(2)](n), the Fe(II) cation is coordinated by two terminal N-bonded thio­cyanate anions and four bridging N:N′-bridging dipyrazin-2-yl di­sulfide ligands in an octa­hedral geometry. The Fe(II) cations are connected via bridging 4,4′-di­pyrazine ligands into chains along the b-axis direction. The asymmetric unit consists of one Fe(II) cation located on position with site symmetry 2/m, one thio­cyanate anion located on a mirror plane and one di­sulfide ligand located on a twofold rotation axis.