catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))]

In the title compound, [Fe(NCS)(2)(C(8)H(6)N(4)S(2))(2)](n), the Fe(II) cation is coordinated by two terminal N-bonded thio­cyanate anions and four bridging N:N′-bridging dipyrazin-2-yl di­sulfide ligands in an octa­hedral geometry. The Fe(II) cations are connected via bridging 4,4′-di­pyrazine liga...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884442/
https://www.ncbi.nlm.nih.gov/pubmed/24426987
http://dx.doi.org/10.1107/S1600536813021958
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author Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description In the title compound, [Fe(NCS)(2)(C(8)H(6)N(4)S(2))(2)](n), the Fe(II) cation is coordinated by two terminal N-bonded thio­cyanate anions and four bridging N:N′-bridging dipyrazin-2-yl di­sulfide ligands in an octa­hedral geometry. The Fe(II) cations are connected via bridging 4,4′-di­pyrazine ligands into chains along the b-axis direction. The asymmetric unit consists of one Fe(II) cation located on position with site symmetry 2/m, one thio­cyanate anion located on a mirror plane and one di­sulfide ligand located on a twofold rotation axis.
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spelling pubmed-38844422014-01-14 catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))] Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(NCS)(2)(C(8)H(6)N(4)S(2))(2)](n), the Fe(II) cation is coordinated by two terminal N-bonded thio­cyanate anions and four bridging N:N′-bridging dipyrazin-2-yl di­sulfide ligands in an octa­hedral geometry. The Fe(II) cations are connected via bridging 4,4′-di­pyrazine ligands into chains along the b-axis direction. The asymmetric unit consists of one Fe(II) cation located on position with site symmetry 2/m, one thio­cyanate anion located on a mirror plane and one di­sulfide ligand located on a twofold rotation axis. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884442/ /pubmed/24426987 http://dx.doi.org/10.1107/S1600536813021958 Text en © Wöhlert et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Jess, Inke
Näther, Christian
catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))]
title catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))]
title_full catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))]
title_fullStr catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))]
title_full_unstemmed catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))]
title_short catena-Poly[[bis­(thio­cyanato-κN)iron(II)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) N (4):N (4′))]
title_sort catena-poly[[bis­(thio­cyanato-κn)iron(ii)]-bis­(μ-dipyrazin-2-yl di­sulfide-κ(2) n (4):n (4′))]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884442/
https://www.ncbi.nlm.nih.gov/pubmed/24426987
http://dx.doi.org/10.1107/S1600536813021958
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