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N′-[(E)-1-(2-Hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide

The title compound, C(13)H(12)N(4)O(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. Mol­ecule B is planar to within 0.044 (3) Å for all non-H atoms, while mol­ecule A is slightly twisted, with a dihedral angle of 6.29 (4)° between the mean planes of the pyrazine-2-...

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Autores principales: Hameed, Shahid, Ahmad, Mushtaq, Tahir, M. Nawaz, Israr, Muhammad, Anwar, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884444/
https://www.ncbi.nlm.nih.gov/pubmed/24427054
http://dx.doi.org/10.1107/S1600536813022137
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author Hameed, Shahid
Ahmad, Mushtaq
Tahir, M. Nawaz
Israr, Muhammad
Anwar, Muhammad
author_facet Hameed, Shahid
Ahmad, Mushtaq
Tahir, M. Nawaz
Israr, Muhammad
Anwar, Muhammad
author_sort Hameed, Shahid
collection PubMed
description The title compound, C(13)H(12)N(4)O(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. Mol­ecule B is planar to within 0.044 (3) Å for all non-H atoms, while mol­ecule A is slightly twisted, with a dihedral angle of 6.29 (4)° between the mean planes of the pyrazine-2-carbohydrazide and 1-(2-hy­droxy­phen­yl)ethanone moieties (r.m.s. deviations = 0.0348 and 0.0428 Å, respectively). S(5) and S(6) ring motifs are formed in both mol­ecules due to the presence of intra­molecular O—H⋯N and N—H⋯N hydrogen bonds. In the crystal, mol­ecules A and B are linked by a C—H⋯O hydrogen bond. They stack along the a-axis direction, forming columns with π–π inter­actions involving inversion-related pyrazine and benzene rings [centroid–centroid distances = 3.5489 (13)–3.8513 (16) Å].
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spelling pubmed-38844442014-01-14 N′-[(E)-1-(2-Hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide Hameed, Shahid Ahmad, Mushtaq Tahir, M. Nawaz Israr, Muhammad Anwar, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(12)N(4)O(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. Mol­ecule B is planar to within 0.044 (3) Å for all non-H atoms, while mol­ecule A is slightly twisted, with a dihedral angle of 6.29 (4)° between the mean planes of the pyrazine-2-carbohydrazide and 1-(2-hy­droxy­phen­yl)ethanone moieties (r.m.s. deviations = 0.0348 and 0.0428 Å, respectively). S(5) and S(6) ring motifs are formed in both mol­ecules due to the presence of intra­molecular O—H⋯N and N—H⋯N hydrogen bonds. In the crystal, mol­ecules A and B are linked by a C—H⋯O hydrogen bond. They stack along the a-axis direction, forming columns with π–π inter­actions involving inversion-related pyrazine and benzene rings [centroid–centroid distances = 3.5489 (13)–3.8513 (16) Å]. International Union of Crystallography 2013-08-14 /pmc/articles/PMC3884444/ /pubmed/24427054 http://dx.doi.org/10.1107/S1600536813022137 Text en © Hameed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hameed, Shahid
Ahmad, Mushtaq
Tahir, M. Nawaz
Israr, Muhammad
Anwar, Muhammad
N′-[(E)-1-(2-Hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide
title N′-[(E)-1-(2-Hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide
title_full N′-[(E)-1-(2-Hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide
title_fullStr N′-[(E)-1-(2-Hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide
title_full_unstemmed N′-[(E)-1-(2-Hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide
title_short N′-[(E)-1-(2-Hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide
title_sort n′-[(e)-1-(2-hy­droxy­phen­yl)ethyl­idene]pyrazine-2-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884444/
https://www.ncbi.nlm.nih.gov/pubmed/24427054
http://dx.doi.org/10.1107/S1600536813022137
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