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N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide
The title compound, C(13)H(12)N(4)O(2), crystallized with two independent molecules (A and B) in the asymmetric unit. Molecule B is planar to within 0.044 (3) Å for all non-H atoms, while molecule A is slightly twisted, with a dihedral angle of 6.29 (4)° between the mean planes of the pyrazine-2-...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884444/ https://www.ncbi.nlm.nih.gov/pubmed/24427054 http://dx.doi.org/10.1107/S1600536813022137 |
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author | Hameed, Shahid Ahmad, Mushtaq Tahir, M. Nawaz Israr, Muhammad Anwar, Muhammad |
author_facet | Hameed, Shahid Ahmad, Mushtaq Tahir, M. Nawaz Israr, Muhammad Anwar, Muhammad |
author_sort | Hameed, Shahid |
collection | PubMed |
description | The title compound, C(13)H(12)N(4)O(2), crystallized with two independent molecules (A and B) in the asymmetric unit. Molecule B is planar to within 0.044 (3) Å for all non-H atoms, while molecule A is slightly twisted, with a dihedral angle of 6.29 (4)° between the mean planes of the pyrazine-2-carbohydrazide and 1-(2-hydroxyphenyl)ethanone moieties (r.m.s. deviations = 0.0348 and 0.0428 Å, respectively). S(5) and S(6) ring motifs are formed in both molecules due to the presence of intramolecular O—H⋯N and N—H⋯N hydrogen bonds. In the crystal, molecules A and B are linked by a C—H⋯O hydrogen bond. They stack along the a-axis direction, forming columns with π–π interactions involving inversion-related pyrazine and benzene rings [centroid–centroid distances = 3.5489 (13)–3.8513 (16) Å]. |
format | Online Article Text |
id | pubmed-3884444 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38844442014-01-14 N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide Hameed, Shahid Ahmad, Mushtaq Tahir, M. Nawaz Israr, Muhammad Anwar, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(12)N(4)O(2), crystallized with two independent molecules (A and B) in the asymmetric unit. Molecule B is planar to within 0.044 (3) Å for all non-H atoms, while molecule A is slightly twisted, with a dihedral angle of 6.29 (4)° between the mean planes of the pyrazine-2-carbohydrazide and 1-(2-hydroxyphenyl)ethanone moieties (r.m.s. deviations = 0.0348 and 0.0428 Å, respectively). S(5) and S(6) ring motifs are formed in both molecules due to the presence of intramolecular O—H⋯N and N—H⋯N hydrogen bonds. In the crystal, molecules A and B are linked by a C—H⋯O hydrogen bond. They stack along the a-axis direction, forming columns with π–π interactions involving inversion-related pyrazine and benzene rings [centroid–centroid distances = 3.5489 (13)–3.8513 (16) Å]. International Union of Crystallography 2013-08-14 /pmc/articles/PMC3884444/ /pubmed/24427054 http://dx.doi.org/10.1107/S1600536813022137 Text en © Hameed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hameed, Shahid Ahmad, Mushtaq Tahir, M. Nawaz Israr, Muhammad Anwar, Muhammad N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide |
title |
N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide |
title_full |
N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide |
title_fullStr |
N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide |
title_full_unstemmed |
N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide |
title_short |
N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide |
title_sort | n′-[(e)-1-(2-hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884444/ https://www.ncbi.nlm.nih.gov/pubmed/24427054 http://dx.doi.org/10.1107/S1600536813022137 |
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