Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate

The asymmetric unit of the title compound, C(21)H(19)N(3)O(3)S, contains two independent mol­ecules. In one mol­ecule, the 1,3-thia­zolidine ring forms dihedral angles of 86.19 (8) and 8.37 (8)° with the phenyl and benzene rings, respectively. The corresponding dihedral angles in the other mol­ecule...

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Autores principales: Mague, Joel T., Akkurt, Mehmet, Mohamed, Shaaban K., Hassan, Alaa A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884445/
https://www.ncbi.nlm.nih.gov/pubmed/24427040
http://dx.doi.org/10.1107/S1600536813021533
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author Mague, Joel T.
Akkurt, Mehmet
Mohamed, Shaaban K.
Hassan, Alaa A.
Albayati, Mustafa R.
author_facet Mague, Joel T.
Akkurt, Mehmet
Mohamed, Shaaban K.
Hassan, Alaa A.
Albayati, Mustafa R.
author_sort Mague, Joel T.
collection PubMed
description The asymmetric unit of the title compound, C(21)H(19)N(3)O(3)S, contains two independent mol­ecules. In one mol­ecule, the 1,3-thia­zolidine ring forms dihedral angles of 86.19 (8) and 8.37 (8)° with the phenyl and benzene rings, respectively. The corresponding dihedral angles in the other mol­ecule are 69.60 (7) and 14.08 (7)°. The dihedral angle between the phenyl and benzene rings is 84.70 (8)° in one mol­ecule and 69.62 (8)° in the other. In the crystal, mol­ecules pack in layers approximately parallel to (10-2). There are weak C—H⋯O hydrogen bonds within these layers. Further weak C—H⋯O hydrogen bonding occurs between the layers to form a three-dimensional network. A weak C—H⋯π inter­action is also observed.
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spelling pubmed-38844452014-01-14 Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate Mague, Joel T. Akkurt, Mehmet Mohamed, Shaaban K. Hassan, Alaa A. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(19)N(3)O(3)S, contains two independent mol­ecules. In one mol­ecule, the 1,3-thia­zolidine ring forms dihedral angles of 86.19 (8) and 8.37 (8)° with the phenyl and benzene rings, respectively. The corresponding dihedral angles in the other mol­ecule are 69.60 (7) and 14.08 (7)°. The dihedral angle between the phenyl and benzene rings is 84.70 (8)° in one mol­ecule and 69.62 (8)° in the other. In the crystal, mol­ecules pack in layers approximately parallel to (10-2). There are weak C—H⋯O hydrogen bonds within these layers. Further weak C—H⋯O hydrogen bonding occurs between the layers to form a three-dimensional network. A weak C—H⋯π inter­action is also observed. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884445/ /pubmed/24427040 http://dx.doi.org/10.1107/S1600536813021533 Text en © Mague et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mague, Joel T.
Akkurt, Mehmet
Mohamed, Shaaban K.
Hassan, Alaa A.
Albayati, Mustafa R.
Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate
title Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate
title_full Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate
title_fullStr Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate
title_full_unstemmed Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate
title_short Methyl (2Z)-((2Z)-2-{(2E)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate
title_sort methyl (2z)-((2z)-2-{(2e)-[1-(4-methyl­phen­yl)ethyl­idene]hydrazinyl­idene}-4-oxo-3-phenyl-1,3-thia­zolidin-5-yl­idene)ethano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884445/
https://www.ncbi.nlm.nih.gov/pubmed/24427040
http://dx.doi.org/10.1107/S1600536813021533
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