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6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline]
In the title compound, [Fe(C(5)H(5))(C(32)H(23)FN(3)OS)], both the thiazolidine ring and the pyrrolidine ring adopt a twist conformation on the N—C(H) bridging bond. Their mean planes are inclined to one another by 10.05 (10)°, and they make dihedral angles of 82.09 (10) and 89.67 (11)°, respective...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884446/ https://www.ncbi.nlm.nih.gov/pubmed/24426996 http://dx.doi.org/10.1107/S1600536813022617 |
| _version_ | 1782298592740900864 |
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| author | Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Gavaskar, Deivasigamani Raghunathan, Raghavachary Velmurugan, Devadasan |
| author_facet | Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Gavaskar, Deivasigamani Raghunathan, Raghavachary Velmurugan, Devadasan |
| author_sort | Suhitha, Sivasubramanian |
| collection | PubMed |
| description | In the title compound, [Fe(C(5)H(5))(C(32)H(23)FN(3)OS)], both the thiazolidine ring and the pyrrolidine ring adopt a twist conformation on the N—C(H) bridging bond. Their mean planes are inclined to one another by 10.05 (10)°, and they make dihedral angles of 82.09 (10) and 89.67 (11)°, respectively, with the cyclopentane ring. The F atom deviates by −0.0238 (2) Å from the benzene ring to which it is attached. In the crystal, molecules are linked by a pair of C—H⋯O hydrogen bonds, forming inversion dimers. |
| format | Online Article Text |
| id | pubmed-3884446 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-38844462014-01-14 6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Gavaskar, Deivasigamani Raghunathan, Raghavachary Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(32)H(23)FN(3)OS)], both the thiazolidine ring and the pyrrolidine ring adopt a twist conformation on the N—C(H) bridging bond. Their mean planes are inclined to one another by 10.05 (10)°, and they make dihedral angles of 82.09 (10) and 89.67 (11)°, respectively, with the cyclopentane ring. The F atom deviates by −0.0238 (2) Å from the benzene ring to which it is attached. In the crystal, molecules are linked by a pair of C—H⋯O hydrogen bonds, forming inversion dimers. International Union of Crystallography 2013-08-17 /pmc/articles/PMC3884446/ /pubmed/24426996 http://dx.doi.org/10.1107/S1600536813022617 Text en © Suhitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Suhitha, Sivasubramanian Gunasekaran, Krishnaswamy Gavaskar, Deivasigamani Raghunathan, Raghavachary Velmurugan, Devadasan 6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
| title | 6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
| title_full | 6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
| title_fullStr | 6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
| title_full_unstemmed | 6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
| title_short | 6-Ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
| title_sort | 6-ferrocenoyl-7-(4-fluorophenyl)spiro[hexahydropyrrolo[1,2-c][1,3]thiazole-5,11′-indeno[1,2-b]quinoxaline] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884446/ https://www.ncbi.nlm.nih.gov/pubmed/24426996 http://dx.doi.org/10.1107/S1600536813022617 |
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