Bis(tri­ethyl­ammonium) chloranilate

In the crystal structure of the title compound [systematic name: bis­(tri­ethyl­ammonium) 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-diolate], 2C(6)H(16)N(+)·C(6)Cl(2)O(4) (2−), the chloranilate anion lies on an inversion center. The tri­ethyl­ammonium cations are linked on both sides of the a...

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Detalles Bibliográficos
Autores principales: Gotoh, Kazuma, Maruyama, Shinpei, Ishida, Hiroyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884448/
https://www.ncbi.nlm.nih.gov/pubmed/24427039
http://dx.doi.org/10.1107/S1600536813021405
Descripción
Sumario:In the crystal structure of the title compound [systematic name: bis­(tri­ethyl­ammonium) 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-diolate], 2C(6)H(16)N(+)·C(6)Cl(2)O(4) (2−), the chloranilate anion lies on an inversion center. The tri­ethyl­ammonium cations are linked on both sides of the anion via bifurcated N—H⋯(O,O) and weak C—H⋯O hydrogen bonds to give a centrosymmetric 2:1 aggregate. The 2:1 aggregates are further linked by C—H⋯O hydrogen bonds into a zigzag chain running along [01-1].

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